The solubility and solution stability are not determined for this product. In general, iodine solutions can be stored at room temperature; however, a literature search is recommended for additional stability considerations.
207772
Iodine
ACS reagent, ≥99.8%, solid
로그인 조직 및 계약 가격 보기
크기 선택
5 G
₩89,320
100 G
₩206,451
4 X 100 G
₩446,397
500 G
₩631,432
1 KG
₩812,812
2.5 KG
₩1,516,004
12 KG
₩5,419,187
제품정보 (DICE 배송 시 비용 별도)
실험식(Hill 표기법):
I2
CAS 번호:
Molecular Weight:
253.81
Beilstein:
3587194
EC Number:
MDL number:
UNSPSC 코드:
12141916
eCl@ss:
38050601
PubChem Substance ID:
NACRES:
NA.21
Grade:
ACS reagent
다음으로 건너뛰기
Grade
ACS reagent
Quality Level
vapor density
9 (vs air)
vapor pressure
0.31 mmHg ( 25 °C)
1 mmHg ( 38.7 °C)
분석
≥99.8%
양식
solid
저항도
1.3E15 μΩ-cm
불순물
≤0.01% nonvolatiles
bp
184 °C (lit.)
mp
113 °C (lit.)
음이온 미량물
Cl- and Br-: ≤0.005%
저장 온도
room temp
SMILES string
II
InChI
1S/I2/c1-2
InChI key
PNDPGZBMCMUPRI-UHFFFAOYSA-N
유사한 제품을 찾으십니까? 방문 제품 비교 안내
1 of 4
이 품목 | 229695 | 326143 | 03002 |
|---|---|---|---|
| form solid | form chips, chunks, pellets | form beads, flakes | form - |
| assay ≥99.8% | assay 99.999% trace metals basis | assay ≥99.99% trace metals basis | assay 99.8-100.5% |
| Quality Level 200 | Quality Level 100 | Quality Level 200 | Quality Level 200 |
| grade ACS reagent | grade - | grade - | grade - |
| anion traces Cl- and Br-: ≤0.005% | anion traces - | anion traces - | anion traces bromide, chloride (as Cl-): ≤250 mg/kg, sulfate (SO42-): ≤50 mg/kg |
| impurities ≤0.01% nonvolatiles | impurities - | impurities - | impurities residual solvents, in accordance, ≤0.03% non-volatile matter |
일반 설명
Iodine exhibits exceptionally high dielectric polarization in various solvents (dioxane, isobutylene, p-xylene and benzene).[1]
애플리케이션
Catalyst for synthesis of esters by condensation of carboxylic acids with alcohols or transfesterification.
A mild and efficient method for esterification and transesterification catalyzed by iodine
A mild and efficient method for esterification and transesterification catalyzed by iodine
Iodine has been used for the easy visualization of 9-bromononanoic acid, allyl ester by thin layer chromatography (TLC).[2] It has also been used for the preparation of oxidation solution, required for the synthesis of oligodeoxynucleotides bearing 3′-terminal phosphorothioate.[3]
Iodine may be used to catalyze:
- Synthesis of 5-(4-nitrophenyl)-10,15,20-triphenylporphyrin.[4]
- Oxidative C-H bond amination of saturated hydrocarbons.[5]
- Protection of amines with benzyloxycarbonyl (Cbz) group.[6]
- Direct oxidative coupling/annulation of β-keto esters or 2-pyridinyl-β-esters with alkenes to form dihydrofurans and indolizine, respectively.[7]
- Thiocyanation of aromatic systems to form aryl thiocyanates.[8]
- Esterification of cellulose with acetic anhydride to form cellulose triacetate.[9]
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT RE 1 Oral - STOT SE 3
표적 기관
Respiratory system, Thyroid
Storage Class Code
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 2
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
An Iodine-Catalyzed Hofmann-Loffler Reaction.
Martinez C and Mu?iz K.
Angewandte Chemie (International Edition in English), 54(28), 8287-8291 (2015)
Iodine catalyzed esterification of cellulose using reduced levels of solvent.
Biswas A, et al.
Carbohydrate Polymers, 68(3), 555-560 (2007)
Iodine/MeOH: a novel and efficient reagent system for thiocyanation of aromatics and heteroaromatics.
Yadav JS, et al.
Tetrahedron Letters, 45(14), 2951-2954 (2004)
Molecular iodine-catalyzed efficient N-Cbz protection of amines.
Varala R, et al.
Journal of the Iranian Chemical Society, 4(3), 370-374 (2007)
Iodine-catalyzed one-pot synthesis of unsymmetrical meso-substituted porphyrins.
Boens B, et al.
Tetrahedron, 66(11), 1994-1996 (2010)
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Can I dilute the powder in ddH2O and store it as such?
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How can I determine the shelf life / expiration / retest date of this product?
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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf도움이 되었습니까?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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