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249491
Tris(4-chlorophenyl)phosphine
95%, powder
Synonim(y):
NSC 136459, Tris(p-chlorophenyl)phosphine
Wybierz wielkość
| Rozmiar/SKU | Dostępność | Cena netto |
|---|---|---|
1 g | Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności | 446,00 zł 379,10 zł |
Informacje o tej pozycji
379,10 zł
Cena katalogowa446,00 złZaoszczędź 15%Nazwa produktu
Tris(4-chlorophenyl)phosphine, 95%
Quality Segment
assay
95%
form
powder
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Cross Couplings
mp
100-103 °C (lit.)
functional group
phosphine
SMILES string
Clc1ccc(cc1)P(c2ccc(Cl)cc2)c3ccc(Cl)cc3
InChI
1S/C18H12Cl3P/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18/h1-12H
InChI key
IQKSLJOIKWOGIZ-UHFFFAOYSA-N
Application
- Preparation of chromans and (E,E)-1,3-dienes via reaction of γ-substituted allenoates with aldehydes
- Solvent-free Heck reactions
Cocatalyst in:
- Regioselective carbomagnesiation of terminal alkynes and enynes with alkyl Grignard reagents
- Rhodium-catalyzed coordination-assisted regioselective alkenylation of aromatic C-H bonds with terminal silylacetylenes
- Rhodium-catalyzed hydrogenation reactions
- Platinum-catalyzed allylation reactions
1 of 1
Ta pozycja | |||
|---|---|---|---|
| description 95% | description 95% | description 97% | description - |
| assay 95% | assay 95% | assay 97% | assay - |
| reaction suitability reaction type: Heck Reaction, reagent type: ligand | reaction suitability reaction type: Stille Coupling, reagent type: ligand | reaction suitability reaction type: Negishi Coupling, reagent type: ligand, reaction type: Sonogashira Coupling, reaction type: Heck Reaction, reaction type: Stille Coupling, reaction type: Hiyama Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction | reaction suitability reagent type: catalyst, core: rhodium |
| functional group phosphine | functional group phosphine | functional group phosphine | functional group - |
| form powder | form liquid | form - | form solid |
| Quality Level 100 | Quality Level 100 | Quality Level 200 | Quality Level 100 |
| mp 100-103 °C (lit.) | mp - | mp 40-43 °C (lit.) | mp 155-156 °C (D) |
![Bis(1,5-cyclooctadiene)rhodium(I) tetrakis[bis(3,5-trifluoromethyl)phenyl]borate](/deepweb/assets/sigmaaldrich/product/structures/275/399/3f196135-3b90-4f6f-95b0-512766f1f5e1/640/3f196135-3b90-4f6f-95b0-512766f1f5e1.png)
Słowo ostrzegawcze
Warning
Kody zagrożeń
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Narządy docelowe
Respiratory system
Klasa składowania
11 - Combustible Solids
Co się dzieje?
WGK 3
Temperatura zapłonu (°F)
Not applicable
Temperatura zapłonu (°C)
Not applicable
PPE (środki ochrony indywidualnej)
dust mask type N95 (US), Eyeshields, Gloves
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