8.08261

Trifluoroacetic anhydride

for synthesis

• Synonim(y): Trifluoroacetic anhydride, Bis(trifluoroacetic) anhydride, TFAA
• Wzór liniowy: (CF₃CO)₂O
• Numer CAS: 407-25-0
• Masa cząsteczkowa: 210.03
• UNSPSC Code: 12352106
• EC Index Number: 206-982-9
• NACRES: NA.22
• MDL number: MFCD00000416
• Assay: ≥99.0% (GC)
• Grade: synthesis grade
• Bp: 40 °C/1013 hPa
• Vapor pressure: 405 hPa ( 20 °C)

Właściwości

• grade: synthesis grade
• Quality Segment: 200
• vapor pressure: 405 hPa ( 20 °C)
• assay: ≥99.0% (GC)
• form: liquid
• dilution: (for synthesis)
• bp: 40 °C/1013 hPa
• mp: -65 °C
• density: 1.51 g/cm³ at 20 °C
• storage temp.: 2-30°C
• SMILES string: FC(F)(F)C(=O)OC(=O)C(F)(F)F
• InChI: 1S/C4F6O3/c5-3(6,7)1(11)13-2(12)4(8,9)10
• InChI key: QAEDZJGFFMLHHQ-UHFFFAOYSA-N

Opis

Application

• Cascade Rearrangement: Nitro Group-Participating Syntheses of 1,2,5-Thiadiazoles and 1,2,4-Thiadiazolones.: This study explores the role of trifluoroacetic anhydride in the synthesis of thiadiazoles and thiadiazolones via a nitro group-participating cascade rearrangement, highlighting its utility in organic synthesis (Li et al., 2024).


• Copper Loading-Controlled Selective Synthesis of 2,5-Bis(trifluoromethyl) and Monotrifluoromethyl-Substituted Oxazoles.: This research demonstrates the selective synthesis of trifluoromethyl-substituted oxazoles using trifluoroacetic anhydride, showcasing its versatility in controlling copper loading during reactions (Wu et al., 2024).


• Wood Esterification by Fatty Acids Using Trifluoroacetic Anhydride as an Impelling Agent and Its Application for the Synthesis of a New Bioplastic.: The study presents a novel method for wood esterification using trifluoroacetic anhydride, facilitating the development of new bioplastic materials (Sejati et al., 2023).


• Synthesis of alpha-Seleno Boronates via Diboration of Carbonyl Compounds.: This paper details the synthesis of alpha-seleno boronates using trifluoroacetic anhydride in the diboration of carbonyl compounds, emphasizing its reactivity and selectivity in chemical transformations (Paul et al., 2023).


• Regioselective Synthesis of 3-Nitroindoles Under Non-Acidic and Non-Metallic Conditions.: The research highlights the use of trifluoroacetic anhydride in the regioselective synthesis of 3-nitroindoles, demonstrating its efficiency under non-acidic and non-metallic conditions (Zhang et al., 2023).

Analysis Note

Assay (GC, area%): ≥ 99.0 % (a/a)
Density (d 20 °C/ 4 °C): 1.509 - 1.512
Identity (IR): passes test

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Informacja o środkach bezpieczeństwa

• Piktogramy: GHS08,GHS05,GHS07
• Słowo ostrzegawcze: Danger
• Ostrzeżenia: P202 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Eye Dam. 1 - Repr. 2 - Skin Corr. 1A
• supp_hazards: EUH014
• Kody zagrożeń: H314,H332,H361d,H412
• Klasa składowania: 8B - Non-combustible corrosive hazardous materials