00375

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl

purum, ≥98.0% (HPLC)

• Wzór empiryczny (zapis Hilla): C₁₁H₂₁N₂O₂
• Numer CAS: 14691-89-5
• Masa cząsteczkowa: 213.30
• UNSPSC Code: 12352005
• NACRES: NA.22
• PubChem Substance ID: 329747053
• EC Number: 423-840-3
• Beilstein/REAXYS Number: 3546225
• MDL number: MFCD00043593
• Assay: ≥98.0% (HPLC)

Właściwości

• grade: purum
• Quality Segment: 200
• assay: ≥98.0% (HPLC)
• greener alternative product score: old score: 9; new score: 8; Find out more about DOZN™ Scoring
• sustainability: Sustainability features
• mp: 143-145 °C (lit.), 143-146 °C
• functional group: amide
• storage temp.: 2-8°C
• SMILES string: CC(=O)NC1CC(C)(C)N([O])C(C)(C)C1
• InChI: 1S/C11H21N2O2/c1-8(14)12-9-6-10(2,3)13(15)11(4,5)7-9/h9H,6-7H2,1-5H3,(H,12,14)
• InChI key: UXBLSWOMIHTQPH-UHFFFAOYSA-N

Opis

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives . This product belongs to category of Re-engineered products, showing key improvements in Green Chemistry Principles “Waste Prevention”, “Safer Solvents and Auxiliaries” and “Inherently Safer Chemistry for Accident Prevention”. Click here to view its DOZN scorecard.

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl undergoes one-electron oxidation and reduction reactions. Reaction products were analyzed by ¹H, ¹³C and ¹⁵N NMR spectral data.

Application

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl radical may be employed in the catalytic system used for the regioselective oxidation of curdlan. It may be employed as model nitroxyl radical to study its reaction with thiophosgene. Reaction afforded 2,2,6,6-tetramethylpiperidine and 2,2,6,6-tetramethyl-1-hydroxypiperidine as major products.

Other Notes

New oxidant for the mild oxidation of alcohols to carbonyls

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Informacja o środkach bezpieczeństwa

• Piktogramy: GHS07
• Słowo ostrzegawcze: Warning
• Kody zagrożeń: H302
• Ostrzeżenia: P264 - P270 - P301 + P312 - P501
• Hazard Classifications: Acute Tox. 4 Oral
• Klasa składowania: 11 - Combustible Solids
• WGK: WGK 1
• PPE (środki ochrony indywidualnej): dust mask type N95 (US), Eyeshields, Gloves
• Temperatura zapłonu (°C): No data available
• Temperatura zapłonu (°F): No data available