- A substrate-unspecified glycosylation reaction promoted by copper(II) trifluoromethanesulfonate in benzotrifluoride.
A substrate-unspecified glycosylation reaction promoted by copper(II) trifluoromethanesulfonate in benzotrifluoride.
Carbohydrate research (2002-03-23)
Hidetoshi Yamada, Tomomi Hayashi
PMID11909590
ABSTRAKT
A glycosylation reaction induced by copper(II) trifluoromethanesulfonate is described. Using benzotrifluoride as the reaction solvent, five kinds of glycosyl donors, a glucosyl chloride, a fluoride, a trichloroacetimidate, a 1-O-acetyl compound, and a lactol were activated to give the corresponding glucosides.
MATERIAŁY
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Opis produktu
Sigma-Aldrich
α,α,α-Trifluorotoluene solution, suitable for NMR (reference standard), 0.05% in benzene-d6 (99.6 atom % D), NMR tube size 3 mm × 8 in.
Sigma-Aldrich
α,α,α-Trifluorotoluene solution, suitable for NMR (reference standard), 0.05% in benzene-d6 (99.6 atom % D)