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线性分子式:
Pd
化学文摘社编号:
分子量:
106.42
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12141733
EC Number:
231-115-6
MDL number:
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产品名称
钯, foil, thickness 0.025 mm, 99.9% trace metals basis
InChI key
KDLHZDBZIXYQEI-UHFFFAOYSA-N
InChI
1S/Pd
SMILES string
[Pd]
assay
99.9% trace metals basis
form
foil
resistivity
9.96 μΩ-cm, 20°C
thickness
0.025 mm
bp
2970 °C (lit.)
mp
1554 °C (lit.)
density
12.02 g/cm3 (lit.)
Quality Level
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此商品 | 287474 | 348643 | GF06365741 |
|---|---|---|---|
| assay 99.9% trace metals basis | assay 99.9% trace metals basis | assay 99.98% trace metals basis | assay 99.95% |
| form foil | form foil | form foil | form foil |
| bp 2970 °C (lit.) | bp 2970 °C (lit.) | bp 2970 °C (lit.) | bp 2970 °C (lit.) |
| density 12.02 g/cm3 (lit.) | density 12.02 g/cm3 (lit.) | density 12.02 g/cm3 (lit.) | density 12.02 g/cm3 (lit.) |
| mp 1554 °C (lit.) | mp 1554 °C (lit.) | mp 1554 °C (lit.) | mp 1554 °C (lit.) |
| resistivity 9.96 μΩ-cm, 20°C | resistivity 9.96 μΩ-cm, 20°C | resistivity 9.96 μΩ-cm, 20°C | resistivity 9.96 μΩ-cm, 20°C |
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Meifang Zheng et al.
Organic letters, 15(8), 1838-1841 (2013-04-02)
Palladium-catalyzed oxidative difunctionalization of enol ethers with 1,3-dicarbonyl compounds to construct trisubstituted furans in one step under mild conditions is described. The reaction is thought to proceed through a C-C bond formation along with a C-O bond closing the ring
Xuxing Chen et al.
Organic & biomolecular chemistry, 11(16), 2582-2585 (2013-03-19)
A one-pot two-step synthesis of versatile indenones has been developed. This palladium(II)-catalyzed transformation involves generation and condensation of ortho-functionalized 1,2-benzils from 2-(2-arylethynylphenyl)acetonitriles using Ph2SO as the oxidant. The resulting 3-cyanoindenones can be converted to various valuable molecules.
Meng Wang et al.
Organic & biomolecular chemistry, 11(16), 2574-2577 (2013-03-15)
A novel Pd/Cu catalyzed domino reaction for the synthesis of functionalized pyrrolo[1,2-b]pyridazines from readily accessible (hetero)aryl propargyl alcohols and 1-amino-2-bromopyrroles was developed. This cascade process involves a Sonogashira cross-coupling reaction, an isomerization and an intramolecular condensation.
V Volarevic et al.
Journal of B.U.ON. : official journal of the Balkan Union of Oncology, 18(1), 131-137 (2013-04-25)
As novel therapeutic agents relevant to colon cancer therapy are explored continuously, we tested 4 R2edda-type ligand precursors O,O'-dialkyl esters of (S,S)-ethylenediamine-N,N'-di-2-(4-methyl)pentanoic acid (L1.2HCl-L4.2HCl) and corresponding palladium(II) and platinum(II) complexes against the human colon cancer cell lines CaCo-2, SW480 and
Kathrin Ulbrich et al.
The Journal of organic chemistry, 78(8), 4202-4206 (2013-04-03)
Racemic 4-hydroxycyclopentenone, readily derived from furfuryl alcohol, can be transformed via its O-Boc derivative to 4-acyloxy, 4-aryloxy-, 4-amino-, or 4-thio-substituted cyclopentenones with high enantioselectivity by palladium-catalyzed kinetic resolution via nucleophilic allylic substitutions. Applying this methodology, a short formal synthesis of
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