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Merck

923222

Poly(9,9-dioctylfluorenyl-2,7-diyl) end capped with dimethylphenyl

greener alternative

Mw 50,000-150,000 by GPC

别名:

PFO-DMP

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关于此项目

线性分子式:
C16H18(C29H40)n
化学文摘社编号:
MDL number:
NACRES:
NA.23
UNSPSC Code:
12352103

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产品名称

Poly(9,9-dioctylfluorenyl-2,7-diyl) end capped with dimethylphenyl, Mw 50,000-150,000 by GPC

description

Emissive Layer
PL: 421 nm in THF

mol wt

Mw 50,000-150,000 by GPC

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

band gap

2.5 eV

solubility

THF: soluble
chlorobenzene: soluble
chloroform: soluble
dichlorobenzene: soluble

λmax

368 nm in THF

orbital energy

HOMO -5.3 eV 
LUMO -2.8 eV 

greener alternative category

Quality Level

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此商品
443263660124901099
Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

description

PL: 421 nm in THF

description

-

description

-

description

Band gap: 1.8 eV, Limited solubility in CHCl3

mol wt

Mw 50,000-150,000 by GPC

mol wt

-

mol wt

-

mol wt

Mw >50,000 by GPC (GPC standard: PS)

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

sustainability

Greener Alternative Product

sustainability

Greener Alternative Product

sustainability

Greener Alternative Product

band gap

2.5 eV

band gap

-

band gap

-

band gap

-

Application

Highly emissive poly(9,9-dioctylfluorenyl-2, 7-diyl) end capped with dimethylphenyl (PFO-DMP) is a conjugated polymer with white light emision, remarkable thermal stability and high photo- and electroluminescence efficiency[1][2]. PFO-DMP was successfully demonstrated in textile digital printing for organic light emission devices (OLEDs) [2], as well as in high voltage composite separator in Lithium batteries at high rates and low temperatures[3].
PFO-DMPP can be used as an active material in the fabrication of LEDs. The modification with dimethylphenyl end-capping groups can enhance the charge injection and transport characteristics, leading to improved device efficiency and stability. It can be used in applications in OPV devices, particularly as a donor material. The end-capping with dimethylphenyl groups can modify the energy levels and molecular packing, impacting the optical and electrical properties. PFO-DMPP can be utilized as an active layer in organic thin-film transistors (OTFTs) due to its improved charge transport characteristics. The end-capping groups help to enhance the carrier mobility and improve the performance of the transistors. This modification can influence the power conversion efficiency of the OPV cells.

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product belongs to Enabling category of greener alternatives thus aligns with "Design for energy efficency". Hole transport organic materials allow perfect energy level alignment with the absorber layer and therefore efficient charge collection, are prone to degradation in ambient conditions.Click here for more information.

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


历史批次信息供参考:

分析证书(COA)

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Efficient white light emission in conjugated polymer homojunctions.
Ho G K, et al.
Applied Physics Letters, 85, 4576-4578 (2004)
Characterization of digital textile printing and polymer blend (PFO-DMP:P3HT) for application in manufacture of organic diodes emitting white light - WOLEDS.
Da Silva M A T, et al.
Optical Materials, 62, 119-131 (2016)
Overcharge Protection for 4 V Lithium Batteries at High Rates and Low Temperatures.
Chen G, et al.
Journal of the Electrochemical Society, 157, A735-A740 (2010)

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