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MilliporeSigma

450227

Lithium hexafluorophosphate

greener alternative

battery grade, ≥99.99% trace metals basis

Sinónimos:

Lithium phosphorus fluoride

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5 G

$116.00

25 G

$400.00

250 G

$2,730.00

$116.00


Disponible para envío el16 de diciembre de 2025Detalles


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Fórmula lineal:
LiPF6
Número CAS:
Peso molecular:
151.91
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
244-334-7
MDL number:
Assay:
≥99.99% trace metals basis
Grade:
battery grade
Form:
powder

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Nombre del producto

Lithium hexafluorophosphate, battery grade, ≥99.99% trace metals basis

InChI key

AXPLOJNSKRXQPA-UHFFFAOYSA-N

InChI

1S/F6P.Li/c1-7(2,3,4,5)6;/q-1;+1

SMILES string

[Li+].F[P-](F)(F)(F)(F)F

grade

battery grade

assay

≥99.99% trace metals basis

form

powder

reaction suitability

core: lithium

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

impurities

≤100.0 ppm Trace Metal Analysis

mp

200 °C (dec.) (lit.)

greener alternative category

Quality Level

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Este artículo
920371201146308315
form

powder

form

-

form

powder

form

powder

assay

≥99.99% trace metals basis

assay

99.9% trace metals basis

assay

98%

assay

98%

Quality Level

100

Quality Level

200

Quality Level

100

Quality Level

100

grade

battery grade

grade

-

grade

-

grade

-

mp

200 °C (dec.) (lit.)

mp

200 °C (dec.) (lit.)

mp

200 °C (dec.) (lit.)

mp

-

impurities

≤100.0 ppm Trace Metal Analysis

impurities

-

impurities

-

impurities

-

Application

Lithium hexafluorophosphate (LiPF₆) battery grade is designed for battery research. It can be used in the research and development of lithium-ion batteries (LIBs). Its role as a primary electrolyte salt is pivotal due to its high ionic conductivity, electrochemical stability, and compatibility with a wide range of electrode materials. It helps in the formation of a stable solid electrolyte interphase (SEI) on the anode surface, which is essential for the longevity and stability of the battery, reducing the risk of thermal runaway and enhancing the overall safety of lithium-ion batteries. LiPF₆ can be used in the development of ionic liquid electrolytes, which offer advantages such as non-flammability and wider electrochemical windows.[1][2]

Features and Benefits

The product is designed with stringent parameters to fulfill the research needs in batteries. It ensures minimal interference from contaminants in trace metal analysis, providing high-purity results.
  • Exceptional Purity: ≥99.99% purity minimizes contamination from trace metals, ensuring suitability for applications sensitive to even minute impurities.
  • Consistent Performance: Ultra-high purity guarantees consistent performance across various applications, reducing variability and enhancing reliability.
  • High Purity Standard: Ideal as a standard or reagent for trace metal analysis and high-precision analytical techniques, ensuring accurate and reliable results.
  • Battery grade for use in battery applications, ensuring suitability and performance.

General description

Lithium hexafluorophosphate (LiPF₆), battery grade, ≥99.99% trace metals basis comes as a white powder with trace metal impurities < 100.0 ppm. Lithium hexafluorophosphate is a class of electrolytic materials that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.[3][4][5][6]

Other Notes

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Preparation and characterization of lithium hexafluorophosphate for lithium-ion battery electrolyte.

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Danger

Hazard Classifications

Acute Tox. 3 Oral - Skin Corr. 1A - STOT RE 1 Inhalation

target_organs

Bone,Teeth

Clase de almacenamiento

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Proc. Power Sources Conf., 37th, 231-231 (1996)
Infrared spectroscopy studies on stability of dimethyl sulfoxide for application in a Li?air battery
Mozhzhukhina N, et al.
The Journal of Physical Chemistry C, 117(36), 18375-18380 (2013)
M D S Lekgoathi et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 153, 651-654 (2015-10-11)
The structure of LiPF6 has been probed using Raman scattering as well as pXRD and the results are compared and contrasted. The conventional Bragg angle scattering pXRD determines that dry LiPF6 crystallizes in a trigonal structure (Space Group R-3 (148))
Kewei Liu et al.
ACS nano, 9(6), 6041-6049 (2015-06-06)
The two-dimensional single-layer and few-layered graphene exhibit many attractive properties such as large specific surface area and high charge carrier mobility. However, graphene sheets tend to stack together and form aggregates, which do not possess the desirable properties associated with
Shijia Zhao et al.
Nanoscale, 7(5), 1984-1993 (2014-12-30)
Hydrogenated carbon nanomaterials exhibit many advantages in both mechanical and electrochemical properties, and thus have a wide range of potential applications. However, methods to control the hydrogenation and the effect of hydrogenation on the microstructure and properties of the produced

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Lithium-ion batteries offer high energy density and cyclic performance for portable electronic devices.

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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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