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30417

Phosphoric acid

greener alternative

Greener Alternative

puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥85%

Synonym(s):

Orthophosphoric acid

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Size/SKUAvailabilityPrice
1 L

Available to ship TODAYfromMILWAUKEE

$269.00
2.5 L

Available to ship TODAYfromMILWAUKEE

$430.00

About This Item

Linear Formula:
H3PO4
CAS Number:
Molecular Weight:
98.00
MDL number:
EC Number:
231-633-2
UNSPSC Code:
12352106
PubChem Substance ID:
Beilstein/REAXYS Number:
1921286
eCl@ss:
38070202
Assay:
≥85%
Form:
liquid

$269.00


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Quality Segment

agency

USP/NF, reag. ISO, reag. Ph. Eur.

vapor density

3.4 (vs air)

vapor pressure

2.2 mmHg ( 20 °C), 5 mmHg ( 25 °C)

grade

ACS reagent, puriss. p.a.

assay

≥85%

form

liquid

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

impurities

reducing impurities, in accordance, residual solvents, in accordance, substances precipitated by ammonia, in accordance, ≤0.001% KMnO4 red. matter (as O), ≤0.001% heavy metals (as Pb), ≤0.001% in water insoluble matters, ≤0.001% volatile acids (as CH3COOH)

bp

158 °C (lit.)

mp

~40 °C (lit.)

density

1.685 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤2 mg/kg, fluoride (F-): ≤1 mg/kg, nitrate (NO3-): ≤3 mg/kg, phosphite, hypophosphite (as H3PO3): ≤20 mg/kg, phosphite, hypophosphite (as H3PO3): in accordance, sulfate (SO42-): ≤30 mg/kg

SMILES string

OP(O)(O)=O

cation traces

As: ≤0.5 mg/kg, Ca: ≤10 mg/kg, Cd: ≤1 mg/kg, Co: ≤1 mg/kg, Cr: ≤1 mg/kg, Cu: ≤1 mg/kg, Fe: ≤5 mg/kg, K: ≤5 mg/kg, Mg: ≤5 mg/kg, Mn: ≤0.5 mg/kg, Na: ≤20 mg/kg, Ni: ≤1 mg/kg, Pb: ≤1 mg/kg, Sb: ≤2 mg/kg, Zn: ≤2 mg/kg

suitability

passes test for appearance of solution

greener alternative category

InChI

1S/H3O4P/c1-5(2,3)4/h(H3,1,2,3,4)

InChI key

NBIIXXVUZAFLBC-UHFFFAOYSA-N

Gene Information

human ... SRC(6714)

General description

We are committed to bringing you Greener Alternative Products, which belong to one of the four categories of greener alternatives. Phosphoric acid-doped polybenzimidazole (PBI) membranes offer a cleaner path to energy by enabling high-temperature fuel cells that efficiently convert hydrogen into electricity with low emissions. Their durability and proton conductivity make them ideal for sustainable power systems. Click here for more information.

Application


  • Cooperative Rh/Achiral Phosphoric Acid-Enabled [3+3] Cycloannulation of Carbonyl Ylides with Quinone Monoimines: Synthesis of Benzofused Dioxabicyclo[3.2.1]octane Scaffolds.: This study demonstrates the catalytic role of phosphoric acid in a [3+3] cycloannulation reaction, enabling the efficient synthesis of complex organic scaffolds (Tu et al., 2024).

Other Notes

Concentrated phosphoric acid is approx. 85% H3PO4 (aqueous).
The article number 30417-4X2.5L will be discontinued. Please order the single bottle 30417-2.5L which is physically identical with the same exact specifications.
The article number 30417-4X2.5L-M will be discontinued. Please order the single bottle 30417-2.5L-M which is physically identical with the same exact specifications.
The article number 30417-6X1L will be discontinued. Please order the single bottle 30417-1L which is physically identical with the same exact specifications.
The article number 30417-6X1L-M will be discontinued. Please order the single bottle 30417-1L-M which is physically identical with the same exact specifications.

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This Item
04107695017466123
description

puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥85%

description

puriss., meets analytical specification of Ph. Eur., BP, NF, 85.0-88.0%

description

ACS reagent, ≥85 wt. % in H2O

description

crystalline, ≥99.999% trace metals basis

grade

puriss. p.a., ACS reagent

grade

puriss.

grade

ACS reagent

grade

-

assay

≥85%

assay

85.0-88.0%

assay

≥85% H3PO4 basis (by NaOH, titration)

assay

≥99.999% trace metals basis

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

200

agency

reag. ISO, reag. Ph. Eur., USP/NF

agency

-

agency

-

agency

-

form

liquid

form

liquid

form

liquid

form

crystalline

anion traces

phosphite, hypophosphite (as H3PO3): in accordance, phosphite, hypophosphite (as H3PO3): ≤20 mg/kg, chloride (Cl-): ≤2 mg/kg, fluoride (F-): ≤1 mg/kg, nitrate (NO3-): ≤3 mg/kg, sulfate (SO42-): ≤30 mg/kg

anion traces

phosphite, hypophosphite (as H3PO3): in accordance, phosphite, hypophosphite (as H3PO3): ≤30 mg/kg, nitrate (NO3-): ≤5 mg/kg, chloride (Cl-): ≤5 mg/kg, sulfate (SO42-): in accordance, fluoride (F-): ≤5 mg/kg, nitrate (NO3-): in accordance, sulfate (SO42-): ≤50 mg/kg

anion traces

chloride (Cl-): ≤3 ppm, sulfate (SO42-): ≤0.003%, nitrate (NO3-): ≤5 ppm

anion traces

-


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pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

flash_point_f

Not applicable

flash_point_c

Not applicable



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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