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Merck

792071

Spiro-MeOTAD

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99% (HPLC)

Synonym(e):

N2,N2,N2′,N2′,N7,N7,N7′,N7′-octakis(4-Methoxyphenyl)-9,9′-Spirobi[9H-Fluoren]-2,2′,7,7′-Tetramin, Spiro-OMeTAD

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Über diesen Artikel

Empirische Formel (Hill-System):
C81H68N4O8
CAS-Nummer:
Molekulargewicht:
1225.43
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:

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Produktname

Spiro-MeOTAD, 99% (HPLC)

InChI

1S/C81H68N4O8/c1-86-65-29-9-53(10-30-65)82(54-11-31-66(87-2)32-12-54)61-25-45-73-74-46-26-62(83(55-13-33-67(88-3)34-14-55)56-15-35-68(89-4)36-16-56)50-78(74)81(77(73)49-61)79-51-63(84(57-17-37-69(90-5)38-18-57)58-19-39-70(91-6)40-20-58)27-47-75(79)76-48-28-64(52-80(76)81)85(59-21-41-71(92-7)42-22-59)60-23-43-72(93-8)44-24-60/h9-52H,1-8H3

SMILES string

COC(C=C1)=CC=C1N(C2=CC=C(C=C2)OC)C(C=C3)=CC4=C3C(C=CC(N(C5=CC=C(C=C5)OC)C6=CC=C(C=C6)OC)=C7)=C7C84C9=C(C=CC(N(C%10=CC=C(C=C%10)OC)C%11=CC=C(C=C%11)OC)=C9)C%12=C8C=C(N(C%13=CC=C(C=C%13)OC)C%14=CC=C(C=C%14)OC)C=C%12

InChI key

XDXWNHPWWKGTKO-UHFFFAOYSA-N

description

Hole Transport Layer

assay

99% (HPLC)

form

solid

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

243-248 °C

λmax

306 nm in dichloromethane
385 nm in dichloromethane

fluorescence

λem 429 nm in dichloromethane

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Dieser Artikel
923230902500906018
assay

99% (HPLC)

assay

≥98.5% (HPLC)

assay

≥99.9%

assay

>98%

form

solid

form

-

form

powder

form

solid

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

-

sustainability

Greener Alternative Product

sustainability

Greener Alternative Product

sustainability

Greener Alternative Product

sustainability

-

mp

243-248 °C

mp

-

mp

247 °C

mp

-

λmax

306 nm in dichloromethane

λmax

-

λmax

-

λmax

-

Application

Hochmobile Substanz, die für weiße OLEDs verwendet wird, um Lochinjektion und -transport zu verbessern. Es ist die bisher beste Festphasen-Lochtransportsubstanz und wird verwendet, um den flüssigen Elektrolyten von DSSC-Solarzellen zu ersetzen, da es aufgrund seiner kleinen Moleküle ausgezeichnete Porenfülleigenschaften in nanoporösen TiO2-Filmen mit einer Porengröße von etwa 30–50 nm aufweist.

General description

Wir verpflichten uns, Ihnen umweltfreundlichere Alternativprodukte anzubieten, die mit einem oder mehreren der „12 Prinzipien der Grünen Chemie“ im Einklang stehen. Dieses Produkt dient als Hilfsprodukt und wird als Lochtransport-Material für hochleistungsfähige Solarzellen verwendet; daher wurde seine Energieeffizienz verbessert. Weitere Informationen finden Sie hier.

Lagerklasse

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

Chemical compatibility between a hole conductor and organic dye enhances the photovoltaic performance of solid-state dye-sensitized solar cells
Young Soo Kwon,
Journal of Materials Chemistry, 22(17), 8641-8648 (2012)
Lining He et al.
ACS applied materials & interfaces, 4(3), 1704-1708 (2012-03-07)
High-efficiency hybrid solar cells are fabricated using a simple approach of spin coating a transparent hole transporting organic small molecule, 2,2',7,7'-Tetrakis-(N,N-di-4-methoxyphenylamino)-9,9'-spirobifluorene (Spiro-OMeTAD) on silicon nanowires (SiNWs) arrays prepared by electroless chemical etching. The characteristics of the hybrid cells are investigated
Jun Jiang et al.
ChemSusChem, 13(2), 412-418 (2019-11-05)
Perovskite solar cells are sensitive to subtle changes in atmospheric conditions, resulting in problems such as the collapse of the perovskite structure and sharp drops in efficiency. Internal defects are also a big obstacle for high-quality polycrystalline perovskites. At present
Jingqi Liu et al.
Scientific reports, 9(1), 1362-1362 (2019-02-06)
Previously, textile dye sensitised solar cells (DSSCs) woven using photovoltaic (PV) yarns have been demonstrated but there are challenges in their implementation arising from the mechanical forces in the weaving process, evaporation of the liquid electrolyte and partially shaded cells

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Explore the eco-friendly potential of organic thin film transistors (OTFTs) for detecting chemical analytes, identifying viruses, and assisting in health diagnostics. This mini-review highlights challenges of achieving sustainability, safety, and biodegradability of each component of an OTFT sensor.

While dye sensitization as the basis for color photography has been accepted for a very long time,1 attempts to use this principle for the conversion of solar light to electricity generally had resulted only in very low photocurrents, below 100 nA/cm

Research focuses on sustainable and cost-effective power generation systems to meet the growing demand for environmentally friendly energy sources.

Dr. Perini and Professor Correa-Baena discuss the latest research and effort to obtain higher performance and stability of perovskite materials.

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Verwandter Inhalt

Organic electronics utilizes organic conductors and semiconductors for applications in organic photovoltaics, organic light-emitting diodes, and organic field-effect transistors.

In der organischen Elektronik werden organische Leiter und Halbleiter für Anwendungen in der organischen Photovoltaik, organischen Leuchtdioden und organischen Feldeffekttransistoren verwendet.

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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