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Reduction procedure effect on the electrochemical properties of conductive carbon black supported Pt-Pd electrocatalysts.

Reduction procedure effect on the electrochemical properties of conductive carbon black supported Pt-Pd electrocatalysts.

Journal of nanoscience and nanotechnology (2013-06-13)

Jae Young Park, Soo-Jin Park, Yongju Jung, Seok Kim

ZUSAMMENFASSUNG

Conductive carbon black supported Pt-Pd nanocomposites were prepared to study a difference of simultaneously and sequentially reduced Pt-Pd nanocomposites using polyol method. The concentration of Pt-Pd alloyed metals on carbon blacks (CB) was adjusted to 20 wt%. The catalysts could be characterized by transmission electron microscopy, X-ray diffraction and thermogravimetric analysis. The electrochemical activities of Pt-Pd were measured by cyclic voltammograms. As a result, electrochemical active surface area (ESA) value of sequentially deposited Pt-Pd/CB was shown to 66 m2/g, which was higher than 55 m2/g of simultaneously deposited Pt-Pd/CB. Besides, average particle size of sequentially deposited Pt-Pd/CB was calculated to 1.7 nm which was smaller than 2.2 nm of simultaneously deposited Pt-Pd/CB.

MATERIALIEN

Produktnummer

Marke

Produktbeschreibung

Sigma-Aldrich

Platinschwarz, black, powder, ≤20 μm, ≥99.95% trace metals basis

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Palladium, powder, 99.995% trace metals basis

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Platin, foil, thickness 0.025 mm, 99.9% trace metals basis

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Platin, wire, diam. 1.0 mm, 99.9% trace metals basis

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Platin, wire, diam. 0.5 mm, 99.9% trace metals basis

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Platin, wire, diam. 0.5 mm, 99.99% trace metals basis

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Platin, gauze, 52 mesh, 99.9% trace metals basis

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Palladium, powder, <1 μm, ≥99.9% trace metals basis

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