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Merck

772410

PTB7

greener alternative

average Mw 80,000-200,000, PDI ≤3.0

Sinonimo/i:

Poly({4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl}{3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl})

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100 MG

CHF 678.00

CHF 678.00


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Informazioni su questo articolo

Formula empirica (notazione di Hill):
(C41H53FO4S4)n
Numero CAS:
NACRES:
NA.23
UNSPSC Code:
12352103

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Nome del prodotto

PTB7, average Mw 80,000-200,000, PDI ≤3.0

description

Band gap: 1.84 eV

form

solid

mol wt

average Mw 80,000-200,000

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

solubility

chlorobenzene: soluble
chloroform: soluble
dichlorobenzene: soluble

λmax

680 nm (thin film)

orbital energy

HOMO -5.15 eV 
LUMO -3.31 eV 

Mw/Mn

2.4 +/- 0.6

PDI

≤3.0

greener alternative category

Quality Level

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754005794333901099
PTB7 average Mw 80,000-200,000, PDI ≤3.0

Sigma-Aldrich

772410

PTB7

PCPDTBT average Mw 7,000-20,000

Sigma-Aldrich

754005

PCPDTBT

PTB7-Th

Sigma-Aldrich

794333

PTB7-Th

PBDB-T

Sigma-Aldrich

901099

PBDB-T

form

solid

form

solid

form

solid

form

powder

description

Band gap: 1.84 eV

description

Band gap: 1.75 eV

description

Band gap: 1.57 eV, Shiny, purple, fiber-like solid

description

Band gap: 1.8 eV, Limited solubility in CHCl3

mol wt

average Mw 80,000-200,000

mol wt

average Mw 7,000-20,000

mol wt

>145,000

mol wt

Mw >50,000 by GPC (GPC standard: PS)

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

-

greener alternative product characteristics

-

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

sustainability

-

sustainability

-

sustainability

Greener Alternative Product

solubility

chlorobenzene: soluble

solubility

-

solubility

chlorobenzene: soluble, dichlorobenzene: soluble

solubility

chlorobenzene: soluble, dichlorobenzene: soluble

Application

High-Efficiency Organic Solar Cells (OPVs)
OPV Device Structure: ITO/PEDOT:PSS/PTB7 :PC71BM/Ca/Al
  • JSC = 14.9 mA/cm2
  • VOC = 0.75 V
  • FF = 0.69
  • PCE = 7.4%
It is majorly used as an active layer that enhances the overall performance by increasing the light absorption and improving the electron mobility of polymeric solar cells (PSCs).[1][2][3][4]

General description

PTB7 is a semiconducting polymer used in organic photovoltaics with an energy efficiency of 9.15%. It can act as an electron donor with narrow optical band gaps and excellent π-π conjugation while forming a nanocomposite with fullerenes.[5][6]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product belongs to Enabling category of greener alternatives thus aligns with "Design for energy efficency". Hole transport organic materials allow perfect energy level alignment with the absorber layer and therefore efficient charge collection, are prone to degradation in ambient conditions.Click here for more information.

Classe di stoccaggio

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Sylvia J Lou et al.
Journal of the American Chemical Society, 133(51), 20661-20663 (2011-12-01)
Processing additives are used in organic photovoltaic systems to optimize the active layer film morphology. However, the actual mechanism is not well understood. Using X-ray scattering techniques, we analyze the effects of an additive diiodooctane (DIO) on the aggregation of
For the bright future-bulk heterojunction polymer solar cells with power conversion efficiency of 7.4%.
Yongye Liang et al.
Advanced materials (Deerfield Beach, Fla.), 22(20), E135-E138 (2010-07-20)
Absolute measurement of domain composition and nanoscale size distribution explains performance in PTB7: PC71BM solar cells
Collins BA, et al.
Advanced Energy Materials, 3(1), 65-74 (2013)
Effect of Active Layer Thickness on the Performance of Polymer Solar Cells Based on a Highly Efficient Donor Material of PTB7-Th
Zang Y, et al.
The Journal of Physical Chemistry C, 122(29), 16532-16539 (2018)
ZnO: CNT assisted charge transport in PTB7: PCBM blend organic solar cell
Oseni SO, et al.
Journal of alloys and compounds, 748(1), 216-222 (2018)

Articoli

Organic photovoltaics (OPVs) represent a low-cost, lightweight, and scalable alternative to conventional solar cells. While significant progress has been made in the development of conventional bulk heterojunction cells, new approaches are required to achieve the performance and stability necessary to enable commercially successful OPVs.

Professor Chen (Nankai University, China) and his team explain the strategies behind their recent record-breaking organic solar cells, reaching a power conversion efficiency of 17.3%.

The development of high-performance conjugated organic molecules and polymers has received widespread attention in industrial and academic research.

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