397229

Acetanilida

purified by sublimation, ≥99.9%

• Sinónimos: N-fenilacetamida
• Fórmula lineal: CH₃CONHC₆H₅
• Número CAS: 103-84-4
• Peso molecular: 135.16
• Beilstein/REAXYS Number: 606468
• EC Number: 203-150-7
• MDL number: MFCD00008674
• UNSPSC Code: 12352100
• eCl@ss: 39031308
• PubChem Substance ID: 24864694
• NACRES: NA.22

Propiedades

• vapor density: 4.65 (vs air)
• Quality Level: 100
• vapor pressure: 1 mmHg ( 114 °C)
• assay: ≥99.9%
• form: solid
• autoignition temp.: 1004 °F
• purified by: sublimation
• bp: 304 °C (lit.)
• mp: 113-115 °C (lit.)
• functional group: amide
• SMILES string: CC(=O)Nc1ccccc1
• InChI: 1S/C8H9NO/c1-7(10)9-8-5-3-2-4-6-8/h2-6H,1H3,(H,9,10)
• InChI key: FZERHIULMFGESH-UHFFFAOYSA-N

Descripción

General description

Pd(OAc)₂ and Cu(OAc)₂ catalyzed regioselective C-H functionalization/halogenation of acetanilide has been reported to afford ortho-haloacetanilides.[1] Crystal structure of acetanilide has been studied by X-ray diffraction.[2] Photorearrangement of acetanilide has been studied in the presence of β-cyclodextrin (cycloheptaamylose).[3] Two-color REMPI (resonance enhanced multiphoton ionization) and ZEKE (zero kinetic energy photoelectron) spectra of the trans-acetanilide·H₂O complex has been reported.[4] Femtosecond IR spectroscopy of delocalized NH excitations of crystalline acetanilide has been studied.[5] Fries rearrangement of acetanilide over zeolites Y and Beta affords corresponding aminoacetophenones.[6]

Información de seguridad

• pictograms: GHS07
• signalword: Warning
• hcodes: H302
• pcodes: P264 - P270 - P301 + P312 - P501
• Hazard Classifications: Acute Tox. 4 Oral
• Clase de almacenamiento: 11 - Combustible Solids
• wgk_germany: WGK 1
• flash_point_f: 321.8 °F - closed cup
• flash_point_c: 161 °C - closed cup
• ppe: dust mask type N95 (US), Eyeshields, Gloves