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  • Targeted functionalisation of a hierarchically-structured porous coordination polymer crystal enhances its entire function.

Targeted functionalisation of a hierarchically-structured porous coordination polymer crystal enhances its entire function.

Chemical communications (Cambridge, England) (2012-04-21)
Kenji Hirai, Shuhei Furukawa, Mio Kondo, Mikhail Meilikhov, Yoko Sakata, Osami Sakata, Susumu Kitagawa
PMID22516961
ABSTRACT

Spatiospecific functionalisation of a shell crystal was performed in a core-shell crystal of a porous coordination polymer (PCP) via post-synthetic modification (PSM). The shell crystal allowed the core crystal to selectively accumulate N,N-dimethylaniline (DMA) and afford the intense exciplex fluorescence.

MATERIALS
Product Number
Brand
Product Description
407275
Sigma-Aldrich
N,N-Dimethylaniline, purified by redistillation, ≥99.5%
Pricing and availability is not currently available.
D145750
Sigma-Aldrich
N,N-Dimethylaniline, 99%
Pricing and availability is not currently available.
07-4260
Sigma-Aldrich
N,N-Dimethylaniline, SAJ first grade, ≥99.0%
Pricing and availability is not currently available.
515124
Sigma-Aldrich
N,N-Dimethylaniline, ReagentPlus®, 99%
Pricing and availability is not currently available.