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线性分子式:
C6H5CH=CHCH2Cl
化学文摘社编号:
分子量:
152.62
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
220-246-4
MDL number:
跳至
产品名称
肉桂基氯, 95%
InChI key
IWTYTFSSTWXZFU-QPJJXVBHSA-N
InChI
1S/C9H9Cl/c10-8-4-7-9-5-2-1-3-6-9/h1-7H,8H2/b7-4+
SMILES string
ClC\C=C\c1ccccc1
assay
95%
form
liquid
refractive index
n20/D 1.584 (lit.)
bp
108 °C/12 mmHg (lit.)
mp
−19 °C (lit.)
density
1.096 g/mL at 25 °C (lit.)
functional group
chloro
phenyl
storage temp.
2-8°C
Quality Level
1 of 4
此商品 | 302791 | 167703 | 108197 |
|---|---|---|---|
| assay 95% | assay 95% | assay 97% | assay 98% |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| mp −19 °C (lit.) | mp - | mp - | mp 30-33 °C (lit.) |
| density 1.096 g/mL at 25 °C (lit.) | density 0.931 g/mL at 25 °C (lit.) | density 1.254 g/mL at 25 °C (lit.) | density 1.044 g/mL at 25 °C (lit.) |
| bp 108 °C/12 mmHg (lit.) | bp 102-104 °C/12 mmHg (lit.) | bp - | bp 250 °C (lit.) |
| refractive index n20/D 1.584 (lit.) | refractive index n20/D 1.4808 (lit.) | refractive index n20/D 1.464 (lit.) | refractive index - |
Application
肉桂酰氯用于不对称全合成具有生物活性的海洋二萜化合物——氦孔蛋白 C 和 E [1]。
General description
在钯催化剂存在下,肉桂酰氯与芳基和烯基金 (I) 膦烷在 THF 中发生区域选择性反应,得到 α-取代产物 †。
signalword
Warning
Hazard Classifications
Muta. 2 - Repr. 2 - Skin Irrit. 2 - Skin Sens. 1B - STOT RE 2
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
174.2 °F - closed cup
flash_point_c
79 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Juan Carlos Rueda et al.
Polymers, 12(6) (2020-06-26)
Stiff thermosensitive hydrogels (HG) were synthesized by self-crosslinking free radical polymerization of N,N-dimethylacrylamide (DMAA) and N-isopropylacrylamide (NIPAAm), adjusting the degree of swelling by carboxylate-containing sodium acrylate (NaAc) or a 2-oxazoline macromonomer (MM). The formation of hydrogels was possible due to
Wibke Lölsberg et al.
Organic letters, 14(23), 5996-5999 (2012-11-15)
A short and enantioselective total synthesis of helioporins C and E, which are bioactive marine diterpenes containing a serrulatane or amphilectane skeleton, was elaborated. The chirogenic step, i.e. a Cu(I)-catalyzed allylic alkylation of a cinnamyl chloride with methylmagnesium bromide, proceeded
Palladium-catalyzed cross-coupling reactions of organogold(I) phosphanes with allylic electrophiles.
Miguel Peña-López et al.
Organic & biomolecular chemistry, 10(8), 1686-1694 (2012-01-24)
Aryl and alkenylgold(I) phosphanes react regioselectively with allylic electrophiles such as cinnamyl and geranyl halides (bromide, chloride and acetates) under palladium catalysis in THF at 80 °C to afford the α-substitution product with moderate to high yields. When the reaction
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