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Merck

698997

聚(3-己基噻吩-2,5-二基)

regioregular, average Mn 54,000-75,000, electronic grade, 99.995% trace metals basis

别名:

Plexcore® OS 2100, P3HT

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关于此项目

线性分子式:
(C10H14S)n
化学文摘社编号:
UNSPSC Code:
12352103
MDL number:

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产品名称

聚(3-己基噻吩-2,5-二基), regioregular, average Mn 54,000-75,000, electronic grade, 99.995% trace metals basis

grade

electronic grade

assay

99.995% trace metals basis

form

solid

mol wt

average Mn 54,000-75,000

description

(>98% head-to-tail regioregular (HNMR))

mp

238 °C

orbital energy

HOMO 5 eV 
LUMO 3 eV 

OPV device performance

ITO/NiO/P3HT/PC61BM/LiF/Al

  • Short-circuit current density (Jsc): 11.3 mA/cm2
  • Open-circuit voltage (Voc): 0.64 V
  • Fill Factor (FF): 0.69
  • Power Conversion Efficiency (PCE): 5.16 %

ITO/PEDOT:PSS/P3HT:PC61BM (1:08)/Al
  • Short-circuit current density (Jsc): 9.5 mA/cm2
  • Open-circuit voltage (Voc): 0.63 V
  • Fill Factor (FF): 0.68
  • Power Conversion Efficiency (PCE): 5 %

Mw/Mn

≤2.5

semiconductor properties

P-type (mobility=10−4 - 10−1 cm2/V·s)

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Application

高分子质量;超高纯度P3HT最适合用于有机太阳能光电板(OPV)研究和设备。聚(3-己基噻吩-2,5-二基)可以大量地作为场效应(FETs)和太阳能电池有机薄膜半导体层。[1],2

General description

最低空余分子轨道能级为 3.1eV
聚(3-己基噻酚) (P3HT)是一种规整性半导体聚合物。它主要用于有机电子,因为其规律的末端对末端的支链排列方式,使得共轭骨架能够有效Π-Π堆积。因为烷基侧基,P3HT在自然状态下是疏水的。[2]

Legal Information

美国Plextronics公司产品,专利号6,166,172。
Plexcore is a registered trademark of Plextronics, Inc.

Comparable product

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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"Control of active semiconducting layer packing in organic thin film transistors through synthetic tailoring of dielectric materials
Singh R, et al.
Royal Society of Chemistry Advances, 4(56), 29383-29392 (2014)
High sensitivity organic photodiodes with low dark currents and increased lifetimes
Ramuz, M.; Burgi, L.; Winnewisser, C.; et al.
Organic Electronics, 9, 369-376 (2008)
Lei Yang et al.
Physical chemistry chemical physics : PCCP, 14(2), 779-789 (2011-11-26)
Two hole conductor materials, spiro-OMeTAD and P3HT, were compared in solid-state dye-sensitized solar cells. Two organic dyes containing one anchor unit (D35) or two anchor units (M3) were used in the comparison. Absorbed photon to current conversion efficiency close to
Thermally Stable, Efficient Polymer Solar Cells with Nanoscale Control of the Interpenetrating Network Morphology
Ma, W.; et al.
Advances in Functional Materials, 15, 1617-1622 (2005)
Flexible Transistors Exploiting P3HT on Paper Substrate and Graphene Oxide Film as Gate Dielectric: Proof of Concept.
Valentini L, et al.
Science of Advanced Materials, 5(5), 530-533 (2013)

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