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Merck

51788

苯胺

analytical standard

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$42.40

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$128.00

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关于此项目

线性分子式:
C6H5NH2
化学文摘社编号:
分子量:
93.13
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
200-539-3
Beilstein/REAXYS Number:
605631
MDL number:

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产品名称

苯胺, analytical standard

InChI key

PAYRUJLWNCNPSJ-UHFFFAOYSA-N

InChI

1S/C6H7N/c7-6-4-2-1-3-5-6/h1-5H,7H2

SMILES string

Nc1ccccc1

grade

analytical standard

vapor density

3.22 (185 °C, vs air)

vapor pressure

0.7 mmHg ( 25 °C)

assay

≥99.5% (GC)

autoignition temp.

1139 °F

shelf life

limited shelf life, expiry date on the label

expl. lim.

11 %

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

impurities

≤0.1% water
<0.03% nitrobenzene (C6H5NO2)

refractive index

n20/D 1.586 (lit.)
n20/D 1.586

bp

184 °C (lit.)

mp

−6 °C (lit.)

density

1.022 g/mL at 25 °C (lit.)

application(s)

environmental

format

neat

Quality Level

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1 of 4

此商品
1036110242284132934
苯胺 analytical standard

Supelco

51788

苯胺

苯胺 United States Pharmacopeia (USP) Reference Standard

USP

1036110

苯胺

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

technique(s)

-

technique(s)

-

technique(s)

-

application(s)

environmental

application(s)

pharmaceutical

application(s)

-

application(s)

-

format

neat

format

neat

format

-

format

-

Quality Level

100

Quality Level

-

Quality Level

200

Quality Level

200

grade

analytical standard

grade

pharmaceutical primary standard

grade

ACS reagent

grade

-

assay

≥99.5% (GC)

assay

-

assay

≥99.5%

assay

99%

Application

关于适当的仪器技术的更多信息,请参见产品的检验报告。联系技术服务部寻求进一步支持。
已经使用气相色谱法(GC)定量测定分子量及其等同体组成时,使用二十烷酸甲酯作为内标物。[1]

Biochem/physiol Actions

苯胺的急性毒性涉及其在体内活化为4-羟基苯胺和与血红蛋白形成加合物。 在红细胞中,这与铁的释放和高铁血红蛋白的积累以及溶血性贫血和脾脏炎症的发展有关。长期给药时,在脾脏中常可观察到肿瘤形成。

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Dam. 1 - Muta. 2 - Skin Sens. 1 - STOT RE 1

target_organs

Blood

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

158.0 °F - closed cup

flash_point_c

70 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Teaching Innovations in Lipid Science (2007)
Conor J Kearney et al.
Science advances, 7(8) (2021-02-21)
Multimodal single-cell RNA sequencing enables the precise mapping of transcriptional and phenotypic features of cellular differentiation states but does not allow for simultaneous integration of critical posttranslational modification data. Here, we describe SUrface-protein Glycan And RNA-seq (SUGAR-seq), a method that
S A Vaziri et al.
Pharmacogenetics, 11(1), 7-20 (2001-02-24)
Arylamines such as 2-naphthylamine and 4-aminobiphenyl are suspected human bladder procarcinogens that require bioactivation to DNA-reactive species to exert their carcinogenic potential. The goals of the present study were (i) to assay for the presence of the arylamine acetyltransferases NAT1
J S Bus et al.
Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 25(8), 619-626 (1987-08-01)
Aniline and several structurally-related aromatic amines produce spleen tumours in rats given high doses of compound in 2-year bioassay studies. Evaluation of the pathogenesis of the splenic lesions and characterization of the disposition of radiolabelled aniline in animals suggests that
Conghui Tang et al.
Journal of the American Chemical Society, 134(46), 18924-18927 (2012-11-08)
A novel and efficient copper-catalyzed azidation reaction of anilines via C-H activation has been developed. This method, in which the primary amine acts as a directing group by coordinating to the metal center, provides ortho azidation products regioselectively under mild

实验方案

HPLC Analysis of Aniline Homologs on Discovery® C18

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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