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Merck

131377

1,10-Phenanthrolin

≥99%

Synonym(e):

o-phenanthroline

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2.5 G

€ 25,40

5 G

€ 39,70

25 G

€ 101,00

100 G

€ 260,00

€ 25,40

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Über diesen Artikel

Empirische Formel (Hill-System):
C12H8N2
CAS-Nummer:
66-71-7
Molekulargewicht:
180.21
PubChem Substance ID:
24848008
eCl@ss:
39210124
UNSPSC Code:
12352100
NACRES:
NA.22
EC Number:
200-629-2
MDL number:
MFCD00011678

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Produktname

1,10-Phenanthrolin, ≥99%

InChI key

DGEZNRSVGBDHLK-UHFFFAOYSA-N

InChI

1S/C12H8N2/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1/h1-8H

SMILES string

c1cnc2c(c1)ccc3cccnc23

assay

≥99%

form

powder

mp

114-117 °C (lit.)

Quality Level

200

Gene Information

human ... FNTA(2339)

Verwandte Kategorien

Application

1,10-Phenanthroline can be used as:
  • A cathode buffer layer to improve the efficiency of organic solar cells.[1]
  • A conventional chelator to study its efficacy in Fenton′s reaction-luminol chemiluminescence system.[2]
  • A ligand in mild, copper (II)-catalyzed cross-coupling of organoboronic acids and sulfinate salts, leading to aryl- and alkenylsulfones.[3]
  • A versatile ligand employed in the spectrophotometric determination of metals[4] and photocatalytic reduction of carbon dioxide.[5]
  • A building block for metallomacrocycles.[6]

pictograms

Skull and crossbonesEnvironment
GHS06,GHS09

signalword

Danger

hcodes

H301,H410

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Lagerklasse

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

Lot/Batch Number
SDBB6364
MKCV9740
SDBB1067
MKCV3595
STBL1289

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In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

Mitsuhiro Wada et al.
Luminescence : the journal of biological and chemical luminescence, 29(7), 955-958 (2014-01-10)
In vitro screening of a Fe(2+) -chelating effect using a Fenton's reaction-luminol chemiluminescence (CL) system is described. The luminescence between the reactive oxygen species generated by the Fenton's reaction and luminol was decreased on capturing Fe(2+) using a chelator. The
Catalysis by Metal Complexes, 14, 217-217 (1993)
Neville S Ng et al.
Dalton transactions (Cambridge, England : 2003), 42(9), 3196-3209 (2012-12-13)
Copper(II) (1(Cu)-21(Cu)) and previously established experimental anticancer platinum(II) metallointercalator complexes (1(Pt)-16(Pt)) have been prepared and investigated for their antimicrobial properties. These complexes are of the general structure [M(I(L))(A(L))](2+) where I(L) represents functionalised 1,10-phenanthrolines (1(IL)-10(IL)), and A(L) represents 1,2-diaminoethane, 1S,2S- or
Aswan Sci. Technol. Bull., 13, 3-3 (1992)
Fan Yang et al.
Nanomaterials (Basel, Switzerland), 9(7) (2019-07-20)
The development of non-noble metal hydrogen evolution catalysts that can replace Pt is crucial for efficient hydrogen production. Herein, we develop a type of well-dispersed Ni2P on N-doped nanomesh carbon (NC) electrocatalyst by a facile pyrolysis method, which shows excellent
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Questions

1–7 of 7 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. Do you have GMP pharmaceutical grade 1,10-Phenanthroline?

    1 answer

    1. Unfortunately, there are no GMP or pharmaceutical grade products available at this time.

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  4. What is the Department of Transportation shipping information for this product?

    1 answer

    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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  5. What is the difference between 1,10-Phenanthroline Products 131377 and 320056?

    1 answer

    1. Product 320056 is the monohydrate form and 131377 has no specification on water content. Both can make a copper complex, since they are the same ligand.

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  6. Can Product 131377, 1,10-Phenanthroline, be used for cell culture?

    1 answer

    1. Sigma-Aldrich does not have any references for the use of 1,10-phenanthroline in cell culture.

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  7. What is the solubility of Product 131377, 1,10-Phenanthroline?

    1 answer

    1. 1,10-Phenanthroline is soluble in methanol at 500 micrograms per mL, or in water at 3 milligrams per mL. It is also soluble in benzene and acetone.

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