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324868

Kaliumtrimethylsilanolat

90%, technical grade

Synonym(e):

Trimethylsilanol Kaliumsalz

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25 G

€ 182,00

100 G

€ 592,00

1 KG

€ 3.000,00

€ 182,00


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Über diesen Artikel

Lineare Formel:
(CH3)3SiOK
CAS-Nummer:
Molekulargewicht:
128.29
Beilstein:
3560282
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352302
PubChem Substanz-ID:
NACRES:
NA.22

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Qualität

technical grade

Qualitätsniveau

Assay

90%

Form

powder

Konzentration

≤100%

mp (Schmelzpunkt)

135-138 °C (lit.)
135-138 °C

SMILES String

[K+].C[Si](C)(C)[O-]
[K+].C[Si](C)(C)[O-]

InChI

1S/C3H9OSi.K/c1-5(2,3)4;/h1-3H3;/q-1;+1
1S/C3H9OSi.K/c1-5(2,3)4;/h1-3H3;/q-1;+1

InChIKey

LBKJNHPKYFYCLL-UHFFFAOYSA-N
LBKJNHPKYFYCLL-UHFFFAOYSA-N

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Dieser Artikel
24177612669345474
grade

technical grade

grade

-

grade

-

grade

-

concentration

≤100%

concentration

-

concentration

-

concentration

-

assay

90%

assay

98%

assay

≥95%

assay

95%

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

100

form

powder

form

solid

form

solid

form

solid

mp

135-138 °C (lit.)

mp

173-176 °C (lit.)

mp

-

mp

-

Anwendung

Potassium trimethylsilanolate can be used as a reagent in the:
  • Hydrolysis of nitriles to primary amides.[1]
  • Conversion of esters to carboxylic acids,[2] and dialkyl phosphonates to their monoalkyl phosphonates.[3]
  • Synthesis of E-alkenes,[4] and nitrocefin.[5]


It can also be used as a coupling promoter in cross-coupling reaction of aliphatic alkynylsilanols with aryl iodides.[6]

Piktogramme

Corrosion

Signalwort

Danger

H-Sätze

Gefahreneinstufungen

Skin Corr. 1B

Lagerklassenschlüssel

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

Lot/Batch Number

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In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

Tetrahedron Letters, 25, 5831-5831 (1984)
Cross-coupling of alkynylsilanols with aryl halides promoted by potassium trimethylsilanolate
Denmark SE and Tymonko SA
The Journal of Organic Chemistry, 68(23), 9151-9154 (2003)
A practical synthesis of nitrocefin
Lee M, et al.
The Journal of Organic Chemistry, 70(1), 367-369 (2005)
Scope and limitations of sodium and potassium trimethylsilanolate as reagents for conversion of esters to carboxylic acids
Lovric M, et al.
Croatica Chemica Acta. Arhiv Za Kemiju, 80(1), 109-115 (2007)
Alkene synthesis: elimination of arenesulfinic acid from alkyl aryl sulfones using potassium trimethylsilanolate as base
Baker-Glenn CAG, et al.
Tetrahedron Letters, 46(43), 7427-7430 (2005)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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