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Merck

100331

Chloromethyl methyl ether

technical grade

Chloromethyl methyl ether
1 of 1 reviewers received a sample product or took part in a promotion

Sinonimo/i:

MOM chloride, Methoxymethyl chloride, Methyl chloromethyl ether

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25 G

CHF 123.00

100 G

CHF 482.00

CHF 123.00


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Informazioni su questo articolo

Formula condensata:
ClCH2OCH3
Numero CAS:
Peso molecolare:
80.51
Numero CE:
Numero MDL:
Codice UNSPSC:
12352101
ID PubChem:
NACRES:
NA.22

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Grado

technical grade

Livello qualitativo

Tensione di vapore

3.55 psi ( 20 °C)

Saggio

≥92.5%

Stato

liquid

Indice di rifrazione

n20/D 1.396 (lit.)

P. ebollizione

55-57 °C ((lit.))
55-57 °C (lit.)

Densità

1.06 g/mL at 25 °C (lit.)
1.06 g/mL at 25 °C

Gruppo funzionale

chloro
ether

Temperatura di conservazione

2-8°C

Stringa SMILE

COCCl

InChI

[1S/C2H5ClO/c1-4-2-3/h2H2,1H3]
1S/C2H5ClO/c1-4-2-3/h2H2,1H3
[XJUZRXYOEPSWMB-UHFFFAOYSA-N]
XJUZRXYOEPSWMB-UHFFFAOYSA-N

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142670242349471259
assay

≥92.5%

assay

95%

assay

98%

assay

≥99.7%

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

200

form

liquid

form

liquid

form

liquid

form

-

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

-

storage temp.

2-8°C

density

1.06 g/mL at 25 °C (lit.)

density

1.019 g/mL at 25 °C (lit.)

density

1.035 g/mL at 25 °C (lit.)

density

1.48 g/mL at 25 °C (lit.)

bp

55-57 °C ((lit.)), 55-57 °C (lit.)

bp

82 °C (lit.)

bp

89-90 °C (lit.)

bp

60 °C/21 mmHg (lit.)

Applicazioni

Chloromethyl methyl ether (MOM-Cl) can be used as a reagent:
  •  For the introduction of the methoxymethyl (MOM) protecting group by converting alcohols to methoxy methyl (MOM) ethers.[1]
  •  To prepare some methoxymethyl group containing metal complexes coordinated to carbonyl and dipyridyl ligands.[2]        
  • In the preparation of fluorene/chloromethyl methyl ether cross-linked polymers by Friedel-Crafts polymerization.[3]

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 1 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Carc. 1A - Flam. Liq. 2

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

60.8 °F - closed cup

Punto d’infiammabilità (°C)

16 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves


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Jung-Jae Lee et al.
Chemical communications (Cambridge, England), (15)(15), 1962-1963 (2009-04-01)
N-Alkylation of a fluorescent macrocyclic amine in aqueous micellar solution produces enhanced emission; the reaction with chloromethyl methyl ether exhibits autocatalysis.
Bis(Chloromethyl) ether and technical-grade chloromethyl methyl ether.
Report on carcinogens : carcinogen profiles, 11, III56-III57 (2004-01-01)
Bis(chloromethyl) ether and technical-grade chloromethyl methyl ether.
Report on carcinogens : carcinogen profiles, 12, 71-73 (2011-08-19)
Martin A Berliner et al.
The Journal of organic chemistry, 70(23), 9618-9621 (2005-11-05)
[Reaction: see text]. Zinc(II) salts catalyze the reaction between acetals and acid halides to provide haloalkyl ethers in near-quantitative yield. Reactions from millimole to mole scale are typically complete in 1-4 h with 0.01 mol % catalyst. The solutions of
A Blair et al.
Cancer causes & control : CCC, 8(3), 473-490 (1997-05-01)
Epidemiologic evidence on the relation between reactive chemicals and cancer is reviewed. These highly reactive chemicals (acrylonitrile; bis[chloromethyl]ether and chloromethyl methyl ether; 1,3-butadiene, ethylene oxide; formaldehyde; mustard gas; sulfuric acid; and vinyl chloride) vary in use and exposure. All are

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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