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Merck

33130

4-(Dimethylamino)benzaldehyde

≥99% (perchloric acid titration), puriss. p.a., reag. Ph. Eur.

Sinonimo/i:

Ehrlich’s reagent

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100 G

CHF 233.00

1 KG

CHF 2’060.00

CHF 233.00


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Informazioni su questo articolo

Formula condensata:
(CH3)2NC6H4CHO
Numero CAS:
Peso molecolare:
149.19
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
202-819-0
MDL number:
Beilstein/REAXYS Number:
606802

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Nome del prodotto

4-(Dimethylamino)benzaldehyde, puriss. p.a., reag. Ph. Eur., ≥99% (perchloric acid titration)

InChI key

BGNGWHSBYQYVRX-UHFFFAOYSA-N

InChI

1S/C9H11NO/c1-10(2)9-5-3-8(7-11)4-6-9/h3-7H,1-2H3

SMILES string

CN(C)c1ccc(C=O)cc1

agency

USP/NF
reag. Ph. Eur.

grade

puriss. p.a.

assay

≥99% (perchloric acid titration)

ign. residue

≤0.1% (as SO4)

loss

≤0.5% loss on drying

mp

72-75 °C (lit.)
73-75 °C

solubility

ethanol: 0.1 g/10 mL

cation traces

Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤50 mg/kg
K: ≤50 mg/kg
Mg: ≤5 mg/kg
Mn: ≤5 mg/kg
Na: ≤50 mg/kg
Ni: ≤5 mg/kg
Pb: ≤5 mg/kg
Zn: ≤5 mg/kg

Quality Level

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Questo articolo
109762156477D2004
assay

≥99% (perchloric acid titration)

assay

98%

assay

99%

assay

≥99% (TLC)

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

200

solubility

ethanol: 0.1 g/10 mL

solubility

H2O: slightly soluble

solubility

alcohol: passes test (APHA ≤60), hydrochloric acid: passes test

solubility

ethanol: 50 mg/mL

mp

72-75 °C (lit.), 73-75 °C

mp

72-75 °C (lit.)

mp

72-75 °C (lit.)

mp

72-75 °C (lit.)

agency

USP/NF

agency

-

agency

-

agency

-

grade

puriss. p.a.

grade

-

grade

-

grade

-

Application

4-(Dimethylamino)benzaldehyde in micelle (sodium dodecyl sulphate) containing medium may be used for the quantification of hydroxyproline in meat samples by spectrophotometric methods.[1]
Forms colored condensation products (Schiff bases) with pyrroles and primary amines.

General description

4-(Dimethylamino)benzaldehyde is also commonly referred as Ehrlich′s reagent. Its crystal structure has been investigated by X-ray analysis. Its crystals belong to the monoclinic crystal system and exhibits space group P21/n.[2] 4-(Dimethylamino)benzaldehyde exhibits dual fluorescence. Its dipole moment in various excited states has been evaluated using their electronic spectra and Bilot-Kawski theory.[3]

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Skin Sens. 1B

Classe di stoccaggio

11 - Combustible Solids

wgk

WGK 1

flash_point_f

327.2 °F - closed cup

flash_point_c

164 °C - closed cup

ppe

Eyeshields, Gloves, type N95 (US)


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Determination of pyrrole derivatives and hydroxyproline with 4-(dimethylamino) benzaldehyde in a micellar medium.
Esteve-Romero JS, et al.
Analytical Letters, 27(8), 1557-1567 (1994)
4-(Dimethylamino) benzaldehyde.
Gao B and Zhu J-L.
Acta Crystallographica Section E, Structure Reports Online, 64(7), 1182-1182 (2008)
Kawski A, et al.
Chemical Physics Letters, 448(4), 208-212 (2007)
M Stefek et al.
Biochimica et biophysica acta, 1502(3), 398-404 (2000-11-09)
In the present work, pepsin digests of tail tendons from streptozotocin-diabetic rats were found to contain material that reacted rapidly at room temperature with p-dimethylaminobenzaldehyde (Ehrlich's reagent) to give an adduct with an absorbance spectrum characteristic of the Ehrlich chromogen
Rosario Zamora et al.
Journal of agricultural and food chemistry, 52(13), 4166-4171 (2004-06-24)
The Ehrlich reaction was optimized to determine the formation of pyrrolized phospholipids in edible oils in an attempt to understand the color reversion produced during the deodorization of poorly degummed edible oils. The procedure consisted of the treatment of the

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