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Merck

80457

Acido trifluoroacetico

eluent additive for LC-MS, LiChropur, ≥99.0% (GC)

Sinonimo/i:

TFA

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Informazioni su questo articolo

Formula condensata:
CF3COOH
Numero CAS:
Peso molecolare:
114.02
Beilstein:
742035
Numero CE:
Numero MDL:
Codice UNSPSC:
41116105
NACRES:
NB.21

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Densità del vapore

3.9 (vs air)

Livello qualitativo

Tensione di vapore

97.5 mmHg ( 20 °C)

Nome Commerciale

LiChropur

Saggio

≥99.0% (GC)

Stato

liquid

tecniche

LC/MS: suitable

Impurezze

≤0.05% water
≤50 mg/kg total sulfur (as SO4)

Indice di rifrazione

n20/D 1.3 (lit.)

P. ebollizione

72.4 °C (lit.)

Punto di fusione

−15.4 °C (lit.)

Solubilità

water: soluble 10,000 g/L

Densità

1.489 g/mL at 20 °C (lit.)

Anioni in tracce

chloride (Cl-): ≤50 mg/kg
sulfite (SO32-): ≤10 mg/kg

Cationi in tracce

Ag: ≤0.05 mg/kg
Al: ≤0.1 mg/kg
Ba: ≤0.1 mg/kg
Bi: ≤0.5 mg/kg
Ca: ≤0.5 mg/kg
Cd: ≤0.1 mg/kg
Co: ≤0.05 mg/kg
Cr: ≤0.1 mg/kg
Cu: ≤0.05 mg/kg
Fe: ≤1.0 mg/kg
K: ≤1.0 mg/kg
Li: ≤0.1 mg/kg
Mg: ≤1.0 mg/kg
Mn: ≤0.1 mg/kg
Mo: ≤0.05 mg/kg
NH4+: ≤10 mg/kg
Na: ≤1.0 mg/kg
Ni: ≤0.1 mg/kg
Pb: ≤0.05 mg/kg
Sr: ≤0.05 mg/kg
Tl: ≤0.1 mg/kg
Zn: ≤0.1 mg/kg

Assorbanza UV

λ: 260 nm Amax: ≤0.9
λ: 270 nm Amax: ≤0.1
λ: 280 nm Amax: ≤0.08
λ: 290 nm Amax: ≤0.07
λ: 300 nm Amax: ≤0.06
λ: 320 nm Amax: ≤0.05

Stringa SMILE

OC(C(F)(F)F)=O

Compatibilità

passes test for LC-MS

InChI

1S/C2HF3O2/c3-2(4,5)1(6)7/h(H,6,7)
DTQVDTLACAAQTR-UHFFFAOYSA-N

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Questo articolo
T65082995371.08178
grade

eluent additive for LC-MS

grade

-

grade

-

grade

-

assay

≥99.0% (GC)

assay

99%

assay

≥99%

assay

≥99.7% (acidimetric)

Quality Level

100

Quality Level

200

Quality Level

100

Quality Level

200

form

liquid

form

liquid

form

liquid

form

liquid

density

1.489 g/mL at 20 °C (lit.)

density

1.489 g/mL at 20 °C (lit.)

density

1.489 g/mL at 20 °C (lit.)

density

1.489 g/mL at 20 °C (lit.)

vapor density

3.9 (vs air)

vapor density

3.9 (vs air)

vapor density

3.9 (vs air)

vapor density

3.9 (vs air)

Descrizione generale

Trifluoroacetic acid is commonly used as a mobile phase additive in liquid chromatography-mass spectrometry (LC-MS).
Features:
  • Extensive QC testing ensures the highest specifications.        
  • Optimized to improve ionization and resolution.        
  • Extremely low levels of inorganic and organic impurities.       
  • Manufactured specifically for accurate and fast LC-MS.

Applicazioni

Trifluoroacetic acid may be used as a mobile phase additive for the analysis of basic compounds in biological samples using hydrophilic interaction liquid chromatography-electrospray ionization coupled to tandem mass spectrometry (HILIC–ESI/MS/MS) and reversed-phase liquid chromatography coupled to tandem mass spectrometry (RP-LC-MS/MS).[1]

Confezionamento

Clear borosilicate glass, high hydrolytic resistance (Type I)

Note legali

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

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Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1A

Codice della classe di stoccaggio

8B - Non-combustible corrosive hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

>212.0 °F - Pensky-Martens closed cup

Punto d’infiammabilità (°C)

> 100 °C - Pensky-Martens closed cup


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Certificati d'analisi (COA)

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Simple means to alleviate sensitivity loss by trifluoroacetic acid (TFA) mobile phases in the hydrophilic interaction chromatography?electrospray tandem mass spectrometric (HILIC?ESI/MS/MS) bioanalysis of basic compounds
Shou ZW and Naidong W
Journal of Chromatography. B, Biomedical Sciences and Applications, 825(2), 186-192 (2005)

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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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