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Merck

360554

Nitromethane

ACS reagent, ≥95%

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Informazioni su questo articolo

Formula empirica (notazione di Hill):
CH3NO2
Numero CAS:
Peso molecolare:
61.04
UNSPSC Code:
12352102
NACRES:
NA.21
PubChem Substance ID:
EC Number:
200-876-6
Beilstein/REAXYS Number:
1698205
MDL number:
Grade:
ACS reagent
Assay:
≥95%
Bp:
101.2 °C (lit.)
Vapor pressure:
2.7 mmHg ( 20 °C)

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Nome del prodotto

Nitromethane, ACS reagent, ≥95%

InChI key

LYGJENNIWJXYER-UHFFFAOYSA-N

InChI

1S/CH3NO2/c1-2(3)4/h1H3

SMILES string

C[N+]([O-])=O

grade

ACS reagent

vapor density

2.1 (vs air)

vapor pressure

2.7 mmHg ( 20 °C)

assay

≥95%

form

liquid

autoignition temp.

784 °F

expl. lim.

7.3 %, 33 °F

dilution

(for analytical testing)

impurities

≤0.05% water

color

APHA: ≤10

refractive index

n20/D 1.382 (lit.)

pH

6.4 (20 °C, 0.01 g/L)

bp

101.2 °C (lit.)

mp

−29 °C (lit.)

density

1.127 g/mL at 25 °C (lit.)

suitability

clear for appearance

Quality Level

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Questo articolo
2704238.208941601725
Nitromethane ACS reagent, ≥95%

Sigma-Aldrich

360554

Nitromethane

Nitromethane suitable for HPLC, ≥96%

Sigma-Aldrich

270423

Nitromethane

Nitromethane for synthesis

Sigma-Aldrich

8.20894

Nitromethane

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

-

grade

ACS reagent

grade

-

grade

-

grade

pharmaceutical primary standard

assay

≥95%

assay

≥96%

assay

≥98% (GC)

assay

-

form

liquid

form

liquid

form

liquid

form

-

refractive index

n20/D 1.382 (lit.)

refractive index

n20/D 1.382 (lit.)

refractive index

-

refractive index

-

bp

101.2 °C (lit.)

bp

101.2 °C (lit.)

bp

101.2 °C/1013 hPa

bp

-

Application

Nitromethane can be used as a solvent in the:
  • FeCl3-catalyzed Friedel-Crafts alkylation of indoles with alcohols.
  • Cobalt-catalyzed dehydration of aldoximes to nitriles.
  • Chemoselective oxidation of alcohols to carbonyl compounds.
  • Gold-catalyzed hydroarylation of aryl-substituted alkynes.

General description

Nitromethane is an aliphatic nitro compound that is commonly used as a solvent for chemical processing and analysis.
Our premium ACS solvents are ideal for routine chemical synthesis, drying, purification, and critical labware cleaning. They meet or exceed the rigorous standards of the American Chemical Society (ACS), ensuring high-quality results for your research needs.

Premium ACS Solvents: Our solvents meet or exceed the stringent standards set by the American Chemical Society, ensuring high quality and reliability for your laboratory applications.

Replicable and Publishable Results: Designed for consistency, our solvents deliver results that can be reliably reproduced, making them ideal for research that requires publication.

Versatile Applications: Suitable for routine chemical synthesis, drying, purification, and critical labware cleaning, our solvents cater to a wide range of research needs in the laboratory.

signalword

Warning

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 3 - Repr. 2

Classe di stoccaggio

4.1A - Other explosive hazardous materials

wgk

WGK 2

flash_point_f

95.0 °F - closed cup

flash_point_c

35 °C - closed cup


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Metal ion encapsulation: cobalt cages derived from polyamines, formaldehyde, and nitromethane.
Geue RJ, et al.
Journal of the American Chemical Society, 106(19), 5478-5488 (1984)
The catalytic chemistry of nitromethane over Co-ZSM5 and other catalysts in connection with the methane-NOxSCR reaction.
Cowan AD, et al.
J. Catal., 176(2), 329-343 (1998)
Junhong Shan et al.
Chemosphere, 86(4), 323-328 (2011-11-01)
In this study, the effects of pH, bromide and nitrite on the formation of halonitromethanes (HNMs) and trihalomethanes (THMs) from eight amino acids (glycine, alanine, serine, cysteine, aspartic acid, glutamic acid, lysine and histidine) and four amino sugars (glucosamine, galactosamine
Huachang Hong et al.
The Science of the total environment, 444, 196-204 (2012-12-29)
The formations of THMs, HAAs, and HNMs from chlorination and chloramination of water from Jinlan Reservoir were investigated in this study. Results showed that monochloramine rather than chlorine generally resulted in lower concentration of DBPs, and the DBPs formation varied
Ryan R Walvoord et al.
Organic letters, 14(16), 4086-4089 (2012-07-31)
An efficient cross-coupling reaction of aryl halides and nitromethane was developed with the use of parallel microscale experimentation. The arylnitromethane products are precursors for numerous useful synthetic products. An efficient method for their direct conversion to the corresponding oximes and

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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