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Merck

650528

Etilacetato

HPLC Plus, for HPLC, GC, and residue analysis, 99.9%

Sinonimo/i:

EtOAc

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Informazioni su questo articolo

Formula condensata:
CH3COOC2H5
Numero CAS:
Peso molecolare:
88.11
Beilstein:
506104
Numero CE:
Numero MDL:
Codice UNSPSC:
12190000
ID PubChem:
NACRES:
NA.21

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Grado

HPLC Plus

Livello qualitativo

agenzia

suitable for EPA ACB B21-02
suitable for EPA ACB B23-05b

Densità del vapore

3 (20 °C, vs air)

Tensione di vapore

73 mmHg ( 20 °C)

Saggio

99.9%

Stato

liquid

Temp. autoaccensione

801 °F

Limite di esplosione

2.2-11.5 %, 38 °F

tecniche

HPLC: suitable
gas chromatography (GC): suitable

Impurezze

≤0.03% water
≤1.0 ppb Fluorescence (quinine) at 365 nm
≤10 ng/L Pesticide residue analysis (as heptachlor epoxide)

Residuo dopo evaporazione

≤0.0001%

Indice di rifrazione

n20/D 1.3720 (lit.)

P. ebollizione

76.5-77.5 °C (lit.)

Punto di fusione

−84 °C (lit.)

Solubilità

alcohol: soluble(lit.)
chloroform: soluble(lit.)

Densità

0.902 g/mL at 25 °C (lit.)

λ

H2O reference

Assorbanza UV

λ: 256 nm Amax: ≤1.00
λ: 275 nm Amax: ≤0.05
λ: 300 nm Amax: ≤0.03
λ: 325-400 nm Amax: ≤0.005

Compatibilità

suitable for residue analysis

applicazioni

PFAS testing

Formato

neat

Stringa SMILE

CCOC(C)=O

InChI

1S/C4H8O2/c1-3-6-4(2)5/h3H2,1-2H3
XEKOWRVHYACXOJ-UHFFFAOYSA-N

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Questo articolo
43916953744634858
Etilacetato HPLC Plus, for HPLC, GC, and residue analysis, 99.9%

Sigma-Aldrich

650528

Etilacetato

Etilacetato suitable for HPLC, ≥99.8%

Sigma-Aldrich

439169

Etilacetato

Etilacetato ReagentPlus®, ≥99.8%

Sigma-Aldrich

537446

Etilacetato

Etilacetato suitable for HPLC, ≥99.7%

Sigma-Aldrich

34858

Etilacetato

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

technique(s)

GC/MS: suitable, HPLC: suitable

technique(s)

-

technique(s)

GC/MS: suitable, HPLC: suitable

grade

HPLC Plus, for residue analysis

grade

-

grade

-

grade

-

assay

99.9%

assay

≥99.8%

assay

≥99.8%

assay

≥99.7%

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

solubility

alcohol: soluble(lit.), chloroform: soluble(lit.)

solubility

alcohol: soluble(lit.), chloroform: soluble(lit.)

solubility

alcohol: soluble(lit.), chloroform: soluble(lit.), water: soluble

solubility

-

form

liquid

form

liquid

form

liquid

form

liquid

Descrizione generale

Ethyl acetate (EA), a carboxylate ester, is bio-friendly organic solvent with a wide range of industrial applications.[1] Its synthesis by reactive distillation[2][3] and by acceptorless dehydrogenative dimerization of ethanol has been explored.[4] Its ability as an acyl acceptor in the immobilized lipase-mediated preparation of biodiesel from crude vegetable oils has been examined.[5] The complete degradation of ethyl acetate to CO2 using manganese octahedral molecular sieve (OMS-2) has been investigated.[6] EA is an effective alternate solvent of diethyl ether, employed for the concentration of eggs, larvae, and cysts in fecal specimens during the Formalin-ether sedimentation technique.[7] Acetaldehyde is reaction intermediate formed during the oxidative combustion of ethanol and ethyl acetate in the presence of copper oxide embedded on Ce-doped titania surface.[8]

Applicazioni

Suitable for HPLC, spectrophotometry, environmental testing

Confezionamento

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See all the new features here!

Altre note

Discover LiChropur reagents ideal for HPLC or LC-MS analysis

Pittogrammi

FlameExclamation mark

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

Organi bersaglio

Central nervous system

Rischi supp

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

24.8 °F - closed cup

Punto d’infiammabilità (°C)

-4 °C - closed cup


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Maria Nikolantonaki et al.
Analytica chimica acta, 660(1-2), 102-109 (2010-01-28)
As volatile thiols are nucleophiles, they are capable of additional reactions with electrophiles. In enology, this concerns reactions between volatile or non-volatile thiols and oxidized phenolic compounds. Initial studies concerning the reactivity of volatile thiols with polyphenols showed that (+)-catechin
Dynamics and control of an ethyl acetate reactive distillation column.
Vora N and Daoutidis P.
Industrial & Engineering Chemistry Research, 40(3), 833-849 (2001)
Towards a green process for bulk-scale synthesis of ethyl acetate: efficient acceptorless dehydrogenation of ethanol.
Martin Nielsen et al.
Angewandte Chemie (International ed. in English), 51(23), 5711-5713 (2012-04-21)
Investigation of ethyl acetate reactive distillation process.
Kenig EY, et al.
Chemical Engineering Science, 56(21), 6185-6193 (2001)
Catalytic Acetylation Amines with Ethyl Acetate.
Camacho-Camacho C, et al.
Main Group Metal Chemistry, 31(1-2), 13-20 (2008)

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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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