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Merck

151238

Glycidyl methacrylate

97%, contains 100 ppm monomethyl ether hydroquinone as inhibitor

Synonym(s):

2,3-Epoxypropyl methacrylate, Methacrylic acid 2,3-epoxypropyl ester

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About This Item

Empirical Formula (Hill Notation):
C7H10O3
CAS Number:
106-91-2
Molecular Weight:
142.15
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
24849103
EC Number:
203-441-9
Beilstein/REAXYS Number:
2506
MDL number:
MFCD00005137

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Product Name

Glycidyl methacrylate, 97%, contains 100 ppm monomethyl ether hydroquinone as inhibitor

InChI key

VOZRXNHHFUQHIL-UHFFFAOYSA-N

InChI

1S/C7H10O3/c1-5(2)7(8)10-4-6-3-9-6/h6H,1,3-4H2,2H3

SMILES string

CC(=C)C(=O)OCC1CO1

assay

97%

form

liquid

contains

100 ppm monomethyl ether hydroquinone as inhibitor

impurities

0.02% epichlorohydrin

refractive index

n20/D 1.449 (lit.)

bp

189 °C (lit.)

density

1.042 g/mL at 25 °C (lit.)

storage temp.

2-8°C

Quality Level

300

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1 of 4

This Item
7793428.00609M55909
Glycidyl methacrylate 97%, contains 100 ppm monomethyl ether hydroquinone as inhibitor

Sigma-Aldrich

151238

Glycidyl methacrylate

Glycidyl methacrylate ≥97.0% (GC)

Sigma-Aldrich

779342

Glycidyl methacrylate

2,3-Epoxypropyl methacrylate Technipur®

Sigma-Aldrich

8.00609

2,3-Epoxypropyl methacrylate

Methyl methacrylate contains ≤30 ppm MEHQ as inhibitor, 99%

Sigma-Aldrich

M55909

Methyl methacrylate

assay

97%

assay

≥97.0% (GC)

assay

-

assay

99%

storage temp.

2-8°C

storage temp.

-

storage temp.

-

storage temp.

2-8°C

density

1.042 g/mL at 25 °C (lit.)

density

1.075 g/mL at 20 °C, 1.042 g/mL at 25 °C (lit.)

density

1.042 g/mL at 25 °C (lit.), 1.07 g/cm3 at 25 °C

density

0.936 g/mL at 25 °C (lit.)

bp

189 °C (lit.)

bp

189 °C (lit.)

bp

189 °C (lit.)

bp

100 °C (lit.)

form

liquid

form

liquid

form

-

form

-

contains

100 ppm monomethyl ether hydroquinone as inhibitor

contains

~0.01% hydrochinone monomethylether as stabilizer

contains

-

contains

≤30 ppm MEHQ as inhibitor

Application

Glycidyl methacrylate dextran (GMA) has been reported to be used as a biocompatible hydrogel.[1] In situ polymerization of GMA with trimethylolpropane trimethacrylate to form macroporous sorbents has also been reported.[2] GMA may also be grafted onto polypropylene.[3]

General description

Glycidyl methacrylate (GMA) is a polyfunctional monomer. It acts as an adhesion promoting crosslinking co-monomer for acrylic and vinyl resins. It is also a reactive colorless diluent. GMA is soluble in ethanol, acetone, diethyl ether, benzene.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Carc. 1B - Eye Dam. 1 - Muta. 2 - Repr. 1B - Skin Corr. 1C - Skin Sens. 1 - STOT RE 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

168.8 °F - closed cup

flash_point_c

76 °C - closed cup

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Certificates of Analysis (COA)

Lot/Batch Number
MKCT1330
MKCS4132
MKCS2090
MKCR9005
MKCT9573

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Styrene-assisted melt free radical grafting of glycidyl methacrylate onto polypropylene
Cartier H and Hu GH
Journal of Polymer Science Part A: Polymer Chemistry, 36(7), 1053-1063 (1998)
Molded? macroporous poly (glycidyl methacrylate-co-trimethylolpropane trimethacrylate) materials with fine controlled porous properties: preparation of monoliths using photoinitiated polymerization
Viklund C, et al
Chemistry of Materials, 9(2), 463-471 (1997)
Synthesis, characterization, and polymerization of glycidyl methacrylate derivatized dextran.
van Dijk-Wolthuis WNE, et al.
Macromolecules, 28(18), 6317-6322 (1995)
Laura Sola et al.
Journal of chromatography. A, 1270, 324-329 (2012-12-04)
Capillary electrophoresis (CE) is one of the most powerful techniques for the separation of biomolecules. However, the separation efficiency of proteins in CE is often compromised by their tendency to interact with the silanol groups on the surface of the
Liang Yuan et al.
Analytical chemistry, 83(17), 6800-6809 (2011-08-03)
A signal amplification strategy for sensitive detection of tumor necrosis factor-alpha (TNF-α) using quantum dots (QDs)-polymer-functionalized silica nanosphere as the label was proposed. In this approach, silica nanospheres with good monodispersity and uniform structure were employed as carriers for surface-initiated
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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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