Thiazolidine-2-carboxylic acid

Name: Thiazolidine-2-carboxylic acid
Brand: ALDRICH
Price: 332 PLN

97%

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5 G

332,00 zł

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Informacje o tej pozycji

Wzór empiryczny (zapis Hilla):

C₄H₇NO₂S

Numer CAS:

65126-70-7

Masa cząsteczkowa:

133.17

NACRES:

NA.22

PubChem Substance ID:

24870454

UNSPSC Code:

12352100

MDL number:

MFCD00068005

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Nazwa produktu

Thiazolidine-2-carboxylic acid, 97%

InChI

1S/C4H7NO2S/c6-4(7)3-5-1-2-8-3/h3,5H,1-2H2,(H,6,7)

SMILES string

OC(=O)C1NCCS1

InChI key

ULSZVNJBVJWEJE-UHFFFAOYSA-N

assay

97%

mp

176 °C (lit.)

functional group

carboxylic acid
thioether

Quality Level

100

Powiązane kategorie

Chemical Building Blocks

Heterocyclic Building Blocks

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Ta pozycja	328464	251089	512362
Sigma-Aldrich 467995 Thiazolidine-2-carboxylic acid	Sigma-Aldrich 328464 2-Azetidinone	Sigma-Aldrich 251089 2-(Methylthio)pyridine-3-carboxylic acid	Sigma-Aldrich 512362 3-Methylpyridine-2-carboxylic acid
assay 97%	assay 98%	assay 98%	assay 97%
Quality Level 100	Quality Level 100	Quality Level 100	Quality Level 100
mp 176 °C (lit.)	mp 74-76 °C (lit.)	mp 215-217 °C (lit.)	mp 114-118 °C
functional group carboxylic acid	functional group -	functional group carboxylic acid, thioether	functional group carboxylic acid

Application

Thiazolidine-2-carboxylic acid may be used in the synthesis of azabicycloadducts[1] and 5-aryl-2,3-dihydropyrrolo[2,1-b]thiazole-6,7-dimethanol 6,7-bis(isopropylcarbamates).[2]

General description

Thiazolidine-2-carboxylic acid (β-thiaproline) is a proline analog.[3] It is an important building block of β-lactam antibiotics. Its X-ray photoelectron spectra has been investigated.[4] It has been reported as a physiological substrate of hog kidney D-amino acid oxidase. Thiazolidine-2-carboxylic acid can be synthesized from cysteamine and glyoxylate.[5]

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pictograms

GHS07

signalword

Warning

hcodes

H302 + H312 + H332,H315,H319,H335

pcodes

P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Klasa składowania

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Odwiedź Bibliotekę dokumentów

Action of thiazolidine-2-carboxylic acid, a proline analog, on protein synthesizing systems.

V Busiello et al.

Biochimica et biophysica acta, 564(2), 311-321 (1979-09-27)

Thiazolidine-2-carboxylic acid, or beta-thiaproline, is a proline analog in which the beta methylene group of proline is substituted by a sulfur atom. It has been deomonstrated that beta-thiaproline is activated and transferred to tRNAPro by Escherichia coli and rat liver

Thiazolidine-2-carboxylate derivatives formed from glyoxylate and L-cysteine or L-cysteinylglycine as possible physiological substrates for D-aspartate oxidase.

C L Burns et al.

Biochemical and biophysical research communications, 125(3), 1039-1045 (1984-12-28)

Adducts of glyoxylate with L-cysteine or L-cysteinylglycine were found to be excellent substrates at low concentrations for beef kidney D-aspartate oxidase. Evidence is presented that cis-thiazolidine-2,4-dicarboxylate and its glycine amide are the actual substrates, and that both are converted in

The effect of 2-substituted thiazolidine-4(R)-carboxylic acids on non-protein sulphydryl levels and sulphurtransferase activities in mouse liver and brain.

L Włodek et al.

Biochemical pharmacology, 46(1), 190-193 (1993-07-06)

2-Substituted thiazolidine-4(R)-carboxylic acids (TD) were found to increase the concentration of non-protein sulphydryls (NPSH) and the activity of rhodanese (thiosulphate sulphurtransferase, EC 2.8.1.1) and 3-mercaptopyruvate sulphurtransferase (EC 2.8.1.2) in mouse liver. These properties suggest TDs are potentially hepatoprotective compounds. However

Synthesis and chromatographic properties of selenazolidine-2-carboxylic acid (beta-selenaproline).

C De Marco et al.

The Italian journal of biochemistry, 28(2), 104-110 (1979-03-01)

Thiazolidine-2-carboxylic acid, an adduct of cysteamine and glyoxylate, as a substrate for D-amino acid oxidase.

P F Fitzpatrick et al.

The Journal of biological chemistry, 257(3), 1166-1171 (1982-02-10)

A mixture of cysteamine and glyoxylate, proposed by Hamilton et al. to form the physiological substrate of hog kidney D-amino acid oxidase (Hamilton, G. A., Buckthal, D. J., Mortensen, R. M., and Zerby, K. W. (1979) Proc. Natl. Acad. Sci.

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Produkty

Proline Derivatives and Analogs

Proline analogues are promising candidates for tuning the biological, pharmaceutical, or physicochemical properties of naturally occuring, as well as de novo designed, linear, and, cyclic peptides.

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