Asymmetric hydroamination of non-activated carbon-carbon multiple bonds.

Asymmetric hydroamination of non-activated carbon-carbon multiple bonds.

Dalton transactions (Cambridge, England : 2003) (2007-11-07)

Isabelle Aillaud, Jacqueline Collin, Jérôme Hannedouche, Emmanuelle Schulz

ABSTRACT

The catalysed enantioselective formation of carbon-nitrogen bonds by the hydroamination reaction is reviewed. All examples deal with substrates containing non-activated carbon-carbon multiple bonds which are transformed either via intramolecular or intermolecular reactions. Structurally different complexes already provided nitrogen containing compounds/heterocycles with high enantioselectivities.

MATERIALS

Product Number

Brand

Product Description

80485

Supelco

Activated charcoal, for the determination of AOX, 50-150 μm particle size

484164

Sigma-Aldrich

Carbon, glassy, spherical powder, 2-12 μm, 99.95% trace metals basis

C9157

Sigma-Aldrich

Activated charcoal, suitable for cell culture, suitable for plant cell culture

05105

Supelco

Activated charcoal, powder

05112

Millipore

Activated charcoal, suitable for GC

31616

Supelco

Activated charcoal, puriss. p.a., powder

29238

Supelco

Activated Charcoal Norit^®, Norit^® RBAA-3, rod

633100

Sigma-Aldrich

Carbon, nanopowder, <100 nm particle size (TEM)

C2889

Sigma-Aldrich

Activated charcoal, untreated, granular, 8-20 mesh

GF68195403

Carbon - Vitreous, rod, 100mm, diameter 7.0mm, glassy carbon

GF23723423

Carbon - Vitreous, rod, 200mm, diameter 1.0mm, glassy carbon

GF61808889

Carbon - Vitreous, foil, 100x100mm, thickness 2.0mm, glassy carbon

GF80419035

Carbon - Vitreous, foil, 8x8mm, thickness 0.5mm, glassy carbon

C5510

Sigma-Aldrich

Activated charcoal, acid-washed with phosphoric and sulfuric acids

C3014

Sigma-Aldrich

Activated charcoal, untreated, granular, 20-60 mesh

C7606

Sigma-Aldrich

Activated Charcoal, meets USP testing specifications

C2764

Sigma-Aldrich

Activated charcoal, untreated, granular, ≤5 mm

C4386

Sigma-Aldrich

Activated charcoal, acid-washed with hydrochloric acid

161551

Sigma-Aldrich

Activated charcoal, powder, -100 particle size (mesh), decolorizing

GF27136100

Carbon, foil, 25x25mm, thickness 0.25mm, rigid graphite, fine grain size, 99.997%

GF37642822

Carbon, foil, 500x500mm, thickness 0.35mm, flexible graphite, 99.8%

GF29579787

Carbon, foil, 200x200mm, thickness 1.0mm, rigid graphite, fine grain size, 99.95%

GF34902109

Carbon, foil, 10x10mm, thickness 2.0mm, hOpg

GF41284953

Carbon, foil, 25x25mm, thickness 0.5mm, pyrolytic graphite, 99.99%

GF62540232

Carbon, foil, 25x25mm, thickness 0.25mm, rigid graphite, fine grain size, 99.95%

GF01564017

Carbon, foil, 25x25mm, thickness 0.5mm, rigid graphite, fine grain size, 99.95%

GF26559513

Carbon, foil, 150x150mm, thickness 5.0mm, rigid graphite, medium grain size, 99.5%

GF95868365

Carbon, foil, 150x150mm, thickness 0.125mm, rigid graphite, fine grain size, 99.95%

GF40705512

Carbon, rod, 25mm, diameter 50mm, graphite, 99.95%

GF99536338

Carbon, foil, 500x500mm, thickness 0.2mm, flexible graphite, 99.8%