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Merck

175501

三氟化硼二乙醚

synthesis grade, liquid

同義詞:

三氟化硼乙醚

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關於此項目

線性公式:
BF3 · O(C2H5)2
CAS 編號:
分子量::
141.93
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352106
EC Number:
203-689-8
MDL number:
Beilstein/REAXYS Number:
3909607

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產品名稱

三氟化硼二乙醚,

InChI key

MZTVMRUDEFSYGQ-UHFFFAOYSA-N

InChI

1S/C4H10BF3O/c1-3-9(4-2)5(6,7)8/h3-4H2,1-2H3

SMILES string

CC[O+](CC)[B-](F)(F)F

grade

synthesis grade

vapor density

4.9 (vs air)

vapor pressure

4.2 mmHg ( 20 °C)

form

liquid

expl. lim.

36 %

reaction suitability

core: boron
reagent type: Lewis acid
reagent type: catalyst

refractive index

n20/D 1.344 (lit.)

bp

126-129 °C (lit.)

mp

−58 °C (lit.)

density

1.15 g/mL (lit.)

functional group

ether

storage temp.

2-8°C

Quality Level

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1 of 4

本產品
216607218847307912
reaction suitability

core: boron, reagent type: catalyst, reagent type: Lewis acid

reaction suitability

-

reaction suitability

core: boron, reagent type: Lewis acid, reagent type: catalyst

reaction suitability

core: boron, reagent type: Lewis acid, reagent type: catalyst

functional group

ether

functional group

ether

functional group

ether

functional group

ether

form

liquid

form

liquid

form

liquid

form

liquid

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

100

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

-

storage temp.

-

mp

−58 °C (lit.)

mp

−58 °C (lit.)

mp

−15 °C (lit.)

mp

-

Application

具有广泛用途的路易斯酸试剂
由芳基环丙酮通过 [3+2] 环加成反应制备环戊基和环庚基[b]吲哚的催化剂。[1]

General description

三氟化硼乙醚或三氟化硼乙醚络合物是一种有机化合物,被广泛用作有机合成中便捷的三氟化硼(BF3)源。它也可用作活化亲电子试剂的路易斯酸。

Packaging

建议将25 mL Sure/Seal 瓶作为一次性瓶使用。 反复穿刺可能会导致产品性能下降。

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Related product

產品號碼
描述
訂價

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT RE 1 Inhalation

target_organs

Kidney

存儲類別/等級

3 - Flammable liquids

wgk

WGK 1

flash_point_f

137.3 °F - closed cup

flash_point_c

58.5 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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分析證明 (COA)

Lot/Batch Number

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您可以在文件庫中找到最近購買的產品相關文件。

存取文件庫

European Journal of Organic Chemistry, 5378-5378 (2006)
M S F Lie Ken Jie et al.
Chemistry and physics of lipids, 125(2), 93-101 (2003-09-23)
Methyl santalbate (methyl trans-11-octadecen-9-ynoate) from Sandal wood seed oil, Santalbum alum) was epoxidized to methyl trans-11,12-epoxy-octadec-9-ynoate (1). Treatment of compound 1 with tetrabutylammonium dihydrogentrifluoride, and boron trifluoride etherate gave the corresponding anti- (2a) (57%) and syn- (2b) (35%) fluorohydrin derivatives
George R Pettit et al.
Journal of natural products, 74(9), 1922-1930 (2011-09-09)
The synthesis of bis-steroidal pyrazines derived from 3-oxo-11,21-dihydroxypregna-4,17(20)-diene (4) and glycosylation of a D-ring side chain with α-L-rhamnose have been summarized. Rearrangement of steroidal pyrazine 10 to 14 was found to occur with boron triflouride etherate. Glycosylation of pyrazine 10
U C Reddy et al.
The Journal of organic chemistry, 74(6), 2605-2608 (2009-02-17)
A diastereoselective one-pot, three-component Prins-Friedel-Crafts reaction was developed for the synthesis of 4-aryltetrahydropyran derivatives from the reaction of carbonyl compounds with homoallylic alcohol in the presence of arene promoted by boron trifluoride etherate.
Kevin M McQuaid et al.
Journal of the American Chemical Society, 131(2), 402-403 (2008-12-23)
C-H bond functionalization enables strategically new approaches to the synthesis of complex organic molecules including biologically active compounds, research probes and functional organic materials. To address the shortcomings of transition metal catalyzed processes, we have developed a new approach to

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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