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Merck

248649

氢碘酸

contains ≤1.5% hypophosphorous acid as stabilizer, ACS reagent, ≥47.0%

同義詞:

碘化氢

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關於此項目

經驗公式(希爾表示法):
HI
CAS 編號:
分子量::
127.91
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352106
MDL number:

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產品名稱

氢碘酸, contains ≤1.5% hypophosphorous acid as stabilizer, ACS reagent, ≥47.0%

InChI

1S/HI/h1H

SMILES string

I

InChI key

XMBWDFGMSWQBCA-UHFFFAOYSA-N

grade

ACS reagent

form

liquid

contains

≤1.5% hypophosphorous acid as stabilizer

concentration

≥47.0%

bp

127 °C (lit.)

density

1.5 g/mL at 25 °C

anion traces

bromide, chloride (as Cl-): ≤0.05%
sulfate (SO42-): ≤0.005%

cation traces

Fe: ≤0.001%
heavy metals: ≤0.001%

storage temp.

2-8°C

Quality Level

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1 of 4

本產品
398098210021752851
concentration

≥47.0%

concentration

-

concentration

57 wt. % in H2O

concentration

57 wt. %

grade

ACS reagent

grade

ACS reagent

grade

-

grade

distilled

Quality Level

200

Quality Level

100

Quality Level

100

Quality Level

100

form

liquid

form

liquid

form

liquid

form

liquid

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

bp

127 °C (lit.)

bp

127 °C (lit.)

bp

127 °C (lit.)

bp

127 °C (lit.)

Application

氢酸是碘化氢的水溶液。它是一种强酸。它通常用作各种反应的试剂,例如:
  • 烯烃和炔烃的亲电氢化反应
  • 环氧化物、醚和缩醛的裂解;醇到碘化物的转化   
  • 许多基团的还原剂,包括醌类、α-二酮类、α-酮类、α-环酮类、α-重氮酮类和亚砜     
  • 酮酸的还原环化

氢氧化酸(次磷酸作为稳定剂)可用于制备用于自旋电子和非线性光学应用的苯铵杂化层状金属卤化物钙钛矿

pictograms

CorrosionEnvironment

signalword

Danger

Hazard Classifications

Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

存儲類別/等級

8B - Non-combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


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分析證明 (COA)

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存取文件庫

Siegfried Eigler et al.
Chemical communications (Cambridge, England), 49(67), 7391-7393 (2013-07-19)
The efficiency of reducing agents for the reduction of graphene oxide (GO) could be probed by scanning Raman spectroscopy. A film of graphene flakes derived from GO was probed to be graphene like. We also focus on the surface quality
Viscosities of aqueous hydrochloric acid solutions, and densities and viscosities of aqueous hydroiodic acid solutions.
Nishikata E, et al.
Journal of Chemical and Engineering Data, 26(3), 254-256 (1981)
Efficient reduction of polycyclic quinones, hydroquinones, and phenols with hydriodic acid.
Konieczny M and Harvey RG.
The Journal of Organic Chemistry, 44(26), 4813-4816 (1979)
Weiran Yang et al.
ChemSusChem, 5(7), 1218-1222 (2012-04-12)
HI returns: Hydroiodic acid is a highly selective reducing reagent for a wide variety of substrates. Its application is limited by the formation of iodine and the difficulty in reconverting that iodione back to HI in situ. We report the
Daniel J Weisenberger et al.
Cancer epidemiology, biomarkers & prevention : a publication of the American Association for Cancer Research, cosponsored by the American Society of Preventive Oncology, 24(3), 512-519 (2015-01-15)
The CpG island methylator phenotype (CIMP) represents a subset of colorectal cancers characterized by widespread aberrant DNA hypermethylation at select CpG islands. The risk factors and environmental exposures contributing to etiologic heterogeneity between CIMP and non-CIMP tumors are not known.

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