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Merck

399388

甲酸

greener alternative

ACS reagent, ≥88%

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線性公式:
HCOOH
CAS 編號:
分子量::
46.03
UNSPSC Code:
12352106
NACRES:
NA.21
PubChem Substance ID:
EC Number:
200-579-1
Beilstein/REAXYS Number:
1209246
MDL number:

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產品名稱

甲酸, ACS reagent, ≥88%

InChI key

BDAGIHXWWSANSR-UHFFFAOYSA-N

InChI

1S/CH2O2/c2-1-3/h1H,(H,2,3)

SMILES string

OC=O

grade

ACS reagent

vapor density

1.6 (vs air)

vapor pressure

44.8 mmHg ( 20 °C)

description

dilution test passes test

assay

≥88%

form

liquid

autoignition temp.

1004 °F

expl. lim.

57 %

greener alternative product characteristics

Catalysis
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sustainability

Greener Alternative Product

impurities

≤0.4% Acetic acid

evapn. residue

≤0.002%

color

APHA: ≤15

refractive index

n20/D 1.370 (lit.)

pH

2.2 (20 °C, 2.2 g/L)

bp

100-101 °C (lit.)

mp

8.2-8.4 °C (lit.)

solubility

water: miscible

density

1.22 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤0.001%
sulfate (SO42-): ≤0.002%
sulfite (SO32-): passes test

cation traces

Fe: ≤5 ppm
NH4+: ≤0.005%
heavy metals: ≤5 ppm (by ICP)

greener alternative category

storage temp.

room temp

Quality Level

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本產品
6950763301533015-M
grade

ACS reagent

grade

ACS reagent

grade

ACS reagent, puriss. p.a.

grade

ACS reagent, puriss. p.a.

assay

≥88%

assay

≥96%

assay

≥98%

assay

≥98%

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

100

form

liquid

form

liquid

form

liquid

form

liquid

storage temp.

room temp

storage temp.

-

storage temp.

-

storage temp.

-

solubility

water: miscible

solubility

water: miscible

solubility

-

solubility

-

Application

作为还原剂可更加环保的利用铁催化将醛还原为醇。

快速选择性铁催化醛的转移氢化反应

General description

我们致力于为您提供更环保的替代产品,以符合“绿色化学的12项原则”的一项或多项原则要求。该产品具有增强催化作用。点击此处,获取更多信息。

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B

supp_hazards

存儲類別/等級

3 - Flammable liquids

wgk

WGK 3

flash_point_f

118.4 °F

flash_point_c

48 °C


從最近期的版本中選擇一個:

分析證明 (COA)

Lot/Batch Number

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已經擁有該產品?

您可以在文件庫中找到最近購買的產品相關文件。

存取文件庫

Modification of Pd for formic acid decomposition by support grafted functional groups.
Jones S, et al.
Catalysis, Structure & Reactivity, 1(1), 19-24 (2015)
Carbon dioxide as a raw material: the synthesis of formic acid and its derivatives from CO2.
Leitner W.
Angewandte Chemie (International Edition in English), 34(20), 2207-2221 (1995)
T Kitamoto et al.
Laboratory investigation; a journal of technical methods and pathology, 57(2), 230-236 (1987-08-01)
The purpose of this study was to design a method by which immunoperoxidase staining can be applied to formalin-fixed, paraffin-embedded tissue sections to demonstrate amyloid deposits in cerebral and systemic amyloidotic tissues. We used anti-prion protein, anti-beta-protein, anti-amyloid A, and
Advances in Direct Formic Acid Fuel Cells: Fabrication of Efficient Ir/Pd Nanocatalysts for Formic Acid Electro-Oxidation.
Al-Akraa IM, et al.
International Journal of Electrochemical Science, 10, 3282-3290 (2015)
Pd-Cu/C electrocatalysts synthesized by one-pot polyol reduction toward formic acid oxidation: Structural characterization and electrocatalytic performance.
Wang L, et al.
International Journal of Hydrogen Energy, 40(4), 1726-1734 (2015)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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