跳轉至內容
Merck

D158550

N,N-二甲基甲酰胺

ReagentPlus®, ≥99%

同義詞:

DMF, NSC 5356

登入 檢視組織與合約價格。

選擇尺寸

暫時無法取得訂價和供貨情況

關於此項目

線性公式:
HCON(CH3)2
CAS 編號:
分子量::
73.09
UNSPSC Code:
12352111
NACRES:
NA.21
PubChem Substance ID:
EC Number:
200-679-5
Beilstein/REAXYS Number:
605365
MDL number:
Assay:
≥99%
Bp:
153 °C (lit.)
Vapor pressure:
2.7 mmHg ( 20 °C)

跳轉至

技術服務
需要援助?我們經驗豐富的科學家團隊隨時樂意為您提供支援。
讓我們為您提供幫助

產品名稱

N,N-二甲基甲酰胺, ReagentPlus®, ≥99%

InChI key

ZMXDDKWLCZADIW-UHFFFAOYSA-N

InChI

1S/C3H7NO/c1-4(2)3-5/h3H,1-2H3

SMILES string

[H]C(=O)N(C)C

vapor density

2.5 (vs air)

vapor pressure

2.7 mmHg ( 20 °C)

product line

ReagentPlus®

assay

≥99%

form

liquid

autoignition temp.

833 °F

expl. lim.

15.2 %

dilution

(for general lab use)

impurities

≤0.1% Water (Karl Fischer)

refractive index

n20/D 1.430 (lit.)

pH

6.7

bp

153 °C (lit.)

mp

−61 °C (lit.)

density

0.944 g/mL (lit.)

Quality Level

尋找類似的產品? 前往 產品比較指南

比較類似項目

查看完整比較

Show Differences

1 of 4

本產品
331203199371.03053
Quality Level

100

Quality Level

200

Quality Level

200

Quality Level

300

assay

≥99%

assay

≥99.8% (GC)

assay

≥99.8%

assay

≥99.8% (GC)

form

liquid

form

liquid

form

liquid

form

liquid

pH

6.7

pH

7 (20 °C, 200 g/L)

pH

7 (20 °C, 200 g/L)

pH

7 (20 °C, 200 g/L in H2O)

refractive index

n20/D 1.430 (lit.)

refractive index

n20/D 1.4290-1.4310, n20/D 1.430 (lit.)

refractive index

n20/D 1.430 (lit.)

refractive index

n20/D 1.430 (lit.)

expl. lim.

15.2 %

expl. lim.

15.2 %

expl. lim.

15.2 %

expl. lim.

15.2 %

Application

N,N-二甲基甲酰胺已被用于制备纯聚氨酯以及纳米复合材料溶液。
它可用于以下过程:
  • 合成金纳米颗粒。[1]
  • 毛细管电泳。[2]
  • N,N-二甲基氨基吡啶的区域选择性合成。[3]
  • 合成尿素-N,N-二甲基甲酰胺,一种与尿素比例为3:1的溶剂化物。[4]
多种疏水性有机化合物的溶剂。

General description

N,N-二甲基甲酰胺(DMF)是一种极性有机溶剂,具有广泛的工业应用。[5] 它是许多反应的前体,如甲酰化、氨基羰基化、胺化、酰胺化和氰化。[6] 它与三氯氧磷一起形成 Vilsmeier 试剂,可用于反应性芳族和杂芳族底物的甲酰化反应。[7] 已在238.15K和338.15K之间进行了DMF的介电弛豫实验。[8] 已经研究了DMF与离子液体、铵盐和咪唑盐之间的分子相互作用的热物理性质。[9] 已经研究了硝酸铵与DMF之间的溶质-溶剂相互作用的特征。[10]

Other Notes

适用于多种DMF应用的更为环保的替代品Cyrene (807796)

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B

存儲類別/等級

3 - Flammable liquids

wgk

WGK 2

flash_point_f

135.5 °F - closed cup

flash_point_c

57.5 °C - closed cup


從最近期的版本中選擇一個:

分析證明 (COA)

Lot/Batch Number

未看到正確版本?

如果您需要一個特定的版本,您可以透過批號來尋找特定憑證。

已經擁有該產品?

您可以在文件庫中找到最近購買的產品相關文件。

存取文件庫

Urea-N,N-dimethylformamide (3/1).
Fernandes P, et al.
Acta Crystallographica Section E, Structure Reports Online, 63(12), 4861-4861 (2007)
Capillary electrophoresis in N,N-dimethylformamide.
Porras SP and Kenndler E.
Electrophoresis, 26(17), 3279-3291 (2005)
N,N-dimethylformamide as a reaction medium for metal nanoparticle synthesis.
Pastoriza-Santos I and Liz-Marzan LM.
Advances in Functional Materials, 19(5), 679-688 (2009)
Reaction of chloropyridazines with N,N -dimethylformamide.
Lee WS, et al.
Journal of Heterocyclic Chemistry, 37(6), 1591-1591 (2000)
N,N-Dimethylformamide: much more than a solvent.
Muzart J.
Tetrahedron, 65(40), 8313-8323 (2009)

文章

Discover AdQPhos and its Pd pre-catalysts for selective α-arylation of diverse nucleophiles under mild aqueous conditions without hazardous solvents.

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

Reviews

No rating value

Active Filters

我們的科學家團隊在所有研究領域都有豐富的經驗,包括生命科學、材料科學、化學合成、色譜、分析等.

聯絡技術服務