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139718

Trimethylphenylammonium tribromide

97%, powder

Sustainability features

Synonym(s):

Phenyltrimethylammonium bromide dibromide, Phenyltrimethylammonium bromide-perbromide, Phenyltrimethylammonium tribromide

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Size/SKUAvailabilityPrice
25 g
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$93.50
100 g
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$186.00

About This Item

Linear Formula:
(CH3)3N(Br3)C6H5
CAS Number:
Molecular Weight:
375.93
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
EC Number:
224-127-8
MDL number:
Beilstein/REAXYS Number:
3919459

$93.50


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Product Name

Trimethylphenylammonium tribromide, 97%

Quality Segment

assay

97%

form

powder

reaction suitability

core: ammonium, reaction type: phase-transfer

sustainability

Sustainability features

mp

110-115 °C (dec.) (lit.)

greener alternative category

SMILES string

Br[Br-]Br.C[N+](C)(C)c1ccccc1

InChI

1S/C9H14N.Br3/c1-10(2,3)9-7-5-4-6-8-9;1-3-2/h4-8H,1-3H3;/q+1;-1

InChI key

PRXNKYBFWAWBNZ-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Green Chemistry. This agent enables selective α-bromination and ketone bromination under mild conditions as a stable orange crystalline solid. Its selectivity minimizes side reactions, reducing waste and improving operational safety. Click here for more information.

Application

Brominating reagent for 1,2-addition of bromine to the double bond of α,β-unsaturated compounds.

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This Item
376426301590135321
description

97%

description

97%

description

98%

description

98%

assay

97%

assay

97%

assay

98%

assay

98%

reaction suitability

core: ammonium, reaction type: phase-transfer

reaction suitability

core: ammonium, reaction type: phase-transfer

reaction suitability

reaction type: phase-transfer, reagent type: organic catalyst, core: ammonium

reaction suitability

core: ammonium, reaction type: phase-transfer, reagent type: organic catalyst

form

powder

form

powder

form

crystalline

form

powder

Quality Level

100

Quality Level

100

Quality Level

200

Quality Level

100

mp

110-115 °C (dec.) (lit.)

mp

99-101 °C (lit.)

mp

71-76 °C (lit.)

mp

215 °C (dec.) (lit.)

sustainability

Greener Alternative Product

sustainability

-

sustainability

-

sustainability

-


Pictograms

Corrosion

Signal Word

Danger

Hazard Codes

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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