A change in color of the material indicates oxidation and it will no longer be active as a catalyst.
216666
Tetrakis(triphenylphosphine)palladium(0)
99%, solid
Synonym(s):
Palladium-tetrakis(triphenylphosphine), Pd(PPh3)4
Sign In to View Organizational & Contract Pricing.
Select a Size
Change View
| Size/SKU | Availability | Price |
|---|---|---|
1 g | Estimated to ship onNovember 10, 2026fromMILWAUKEE | $71.00 |
5 g | Estimated to ship onNovember 10, 2026fromMILWAUKEE | $139.00 |
25 g | Estimated to ship onNovember 10, 2026fromMILWAUKEE | $550.00 |
4 x 25 g | Estimated to ship onOctober 20, 2026fromMILWAUKEE | $1,620.00 |
About This Item
Linear Formula:
Pd[(C6H5)3P]4
CAS Number:
Molecular Weight:
1155.56
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
238-086-9
MDL number:
Beilstein/REAXYS Number:
6704828
Product Name
Tetrakis(triphenylphosphine)palladium(0), 99%
Quality Segment
assay
99%
form
solid
reaction suitability
core: palladium, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Buchwald-Hartwig Cross Coupling Reaction
parameter
air sensitive
storage temp.
2-8°C
SMILES string
[Pd].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9.c%10ccc(cc%10)P(c%11ccccc%11)c%12ccccc%12
InChI
1S/4C18H15P.Pd/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H;
InChI key
NFHFRUOZVGFOOS-UHFFFAOYSA-N
General description
Palladium-tetrakis(triphenylphosphine) (Pd(PPh3)4) iscoordination complex of palladium and is widely used palladium cross-coupling catalyst. These applications include Negishi coupling, Suzuki coupling, Stille coupling, Sonogashira coupling, and Buchwald-Hartwig amination reactions.
Tetrakis(triphenylphosphine)palladium(0) (Pd(PPh3)4) is a commonly used palladium(0) complex in chemical synthesis. It plays a vital role as a catalyst in various organic reactions, especially C-C, C-N, C-O, and C-heteroatom cross-coupling reactions. Pd(PPh3)4 finds extensive application in carbon-carbon bond-forming reactions such as the famous Heck, Suzuki-Miyaura, and Stille reactions. These reactions involve the coupling of aryl, alkyl, or vinyl halides with other organic compounds to yield valuable products. The catalytic cycle involves the oxidative addition of the organic halide to palladium(0), transmetalation with a suitable organometallic reagent or boronic acid, and reductive elimination to form the desired product. Pd(PPh3)4 has also been utilized in various other transformations including allylic substitutions, nucleophilic additions to alkenes and alkynes, and cycloadditions.
Tetrakis(triphenylphosphine)palladium(0) (Pd(PPh3)4) is a commonly used palladium(0) complex in chemical synthesis. It plays a vital role as a catalyst in various organic reactions, especially C-C, C-N, C-O, and C-heteroatom cross-coupling reactions. Pd(PPh3)4 finds extensive application in carbon-carbon bond-forming reactions such as the famous Heck, Suzuki-Miyaura, and Stille reactions. These reactions involve the coupling of aryl, alkyl, or vinyl halides with other organic compounds to yield valuable products. The catalytic cycle involves the oxidative addition of the organic halide to palladium(0), transmetalation with a suitable organometallic reagent or boronic acid, and reductive elimination to form the desired product. Pd(PPh3)4 has also been utilized in various other transformations including allylic substitutions, nucleophilic additions to alkenes and alkynes, and cycloadditions.
Application
Tetrakis(triphenylphosphine)palladium(0) can be used as a catalyst in:
- Negishi coupling (eq. 1), Suzuki coupling (eq. 2), Stille coupling (eq. 3), Sonogashira coupling reaction (eq. 4), and Buchwald-Hartwig amination reaction (eq. 5)
- The carbonylation of vinyl iodides (eq. 6)
- The reduction reaction of aryl bromides (eq. 7)
- Carbon-tin bond formation (eq. 8)
1 of 1
This Item | |||
|---|---|---|---|
| description 99% | description ≥99.99% trace metals basis | description 97% | description - |
| assay 99% | assay ≥99.99% trace metals basis | assay 97% | assay - |
| reaction suitability reaction type: Negishi Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst | reaction suitability reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Stille Coupling, reagent type: catalyst, reaction type: Hiyama Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Cross Couplings, reaction type: Heck Reaction, core: palladium | reaction suitability reagent type: catalyst, core: platinum | reaction suitability reaction type: Heck Reaction, reagent type: catalyst |
| form solid | form crystals | form - | form solid |
| Quality Level 200 | Quality Level 200 | Quality Level 100 | Quality Level 100 |
| storage temp. 2-8°C | storage temp. 2-8°C | storage temp. 2-8°C | storage temp. - |
| parameter air sensitive | parameter - | parameter - | parameter - |
Still not finding the right product?
Explore all of our products under Tetrakis(triphenylphosphine)palladium(0)
Signal Word
Warning
Hazard Codes
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral
Storage Class
11 - Combustible Solids
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
PPE (personal protective equipment)
Eyeshields, Gloves, type N95 (US)
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
-
The color of Product 216666, Pd tetrakis(triphenylphosphine)Cl was a yellow or gold color, but now my material has turned a tan, brown, or green color. Is it still good to use?
1 answer-
Helpful?
-
-
What is the Department of Transportation shipping information for this product?
1 answer-
Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.
Helpful?
-