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276286

(1R)-(−)-Camphorquinone

99%

Synonym(s):

(1R)-(−)-2,3-Bornanedione, 2,3-Bornanedione

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Size/SKUAvailabilityPrice
5 g

Available to ship TODAY

$258.00

About This Item

Empirical Formula (Hill Notation):
C10H14O2
CAS Number:
Molecular Weight:
166.22
UNSPSC Code:
12352115
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2327696
Assay:
99%

$258.00


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Quality Segment

assay

99%

optical activity

[α]20/D −101°, c = 2 in toluene

mp

200-203 °C (lit.)

functional group

ketone

SMILES string

CC1(C)[C@@H]2CC[C@@]1(C)C(=O)C2=O

InChI

1S/C10H14O2/c1-9(2)6-4-5-10(9,3)8(12)7(6)11/h6H,4-5H2,1-3H3/t6-,10+/m1/s1

InChI key

VNQXSTWCDUXYEZ-LDWIPMOCSA-N

Application

(1R)-(−)-Camphorquinone can be used as a chiral starting material for the preparation of:
  • α-Hydroxycamphors by selective reduction of keto groups using various vegetables.
  • Camphor-1,2-diamine platinum(II) complexes for DNA interaction studies.
  • Camphoric anhydride by unsensitized photo-oxidation in the presence of oxygen and polar solvents.
  • Camphorquinone-based chiral homoallylic amine, which is reacted with aldehydes to produce homoallylic primary amines via imine formation followed by 2-azonia-Cope rearrangement.

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This Item
28214645985
description

99%

description

98%

description

analytical standard

assay

99%

assay

98%

assay

≥99.0% (sum of enantiomers, GC)

Quality Level

100

Quality Level

100

Quality Level

100

mp

200-203 °C (lit.)

mp

198 °C (dec.) (lit.)

mp

-

optical activity

[α]20/D −101°, c = 2 in toluene

optical activity

[α]20/D −21°, c = 2 in H2O

optical activity

[α]20/D -81±1°, c = 8% in benzene

functional group

ketone

functional group

ketone, sulfonic acid

functional group

-


Pictograms

Health hazardExclamation mark

Signal Word

Danger

Hazard Codes

Hazard Classifications

Acute Tox. 4 Oral - Resp. Sens. 1

Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

dust mask type N95 (US), Eyeshields, Faceshields, Gloves



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