F17407

1-Formylpiperidine

99%

• Synonym(s): N-Carbaldehyde piperidine, NFP, Piperidine-1-carboxaldehyde
• Empirical Formula (Hill Notation): C₆H₁₁NO
• CAS Number: 2591-86-8
• Molecular Weight: 113.16
• UNSPSC Code: 12352100
• NACRES: NA.22
• PubChem Substance ID: 24894793
• EC Number: 219-986-0
• Beilstein/REAXYS Number: 107697
• MDL number: MFCD00006483
• Assay: 99%
• Form: liquid

Properties

• vapor pressure: 0.1 mmHg ( 25 °C)
• Quality Segment: 100
• assay: 99%
• form: liquid
• refractive index: n20/D 1.484 (lit.)
• bp: 222 °C (lit.)
• density: 1.019 g/mL at 25 °C (lit.)
• SMILES string: [H]C(=O)N1CCCCC1
• InChI: 1S/C6H11NO/c8-6-7-4-2-1-3-5-7/h6H,1-5H2
• InChI key: FEWLNYSYJNLUOO-UHFFFAOYSA-N

Description

Application

Reactant for:

• Direct amidation of azoles with formamides via metal-free C-H activation in the presence of tert-butyl perbenzoate
• Vilsmeier-type reactions of pyrazoles with amides in the presence of phosphorous oxychloride
• CO-free aminocarbonylation of N-substituted formamides with aryl iodides/bromides catalyzed by palladium acetate and Xantphos for synthesis of arylamides
• Synthesis of alternating copolymers for organic photovoltaic applications
• One-pot double functionalization of π-deficient heterocyclic lithium reagents
• Synthesis of thermally stable piezofluorochromic aggregation-induced emission compounds

Safety Information

• Pictograms: GHS06
• Signal Word: Danger
• Hazard Codes: H302,H311,H319
• Precautionary Statements: P264 - P280 - P301 + P312 - P302 + P352 + P312 - P305 + P351 + P338 - P337 + P313
• Hazard Classifications: Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Eye Irrit. 2
• Storage Class: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 1
• Flash Point (°F): 215.6 °F - closed cup
• Flash Point (°C): 102 °C - closed cup
• PPE (personal protective equipment): Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter