212792
Lithium aluminum hydride solution
1.0 M in diethyl ether
Synonym(s):
LAH, Lithium alanate, Lithium tetrahydroaluminate
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About This Item
form
liquid
Quality Segment
reaction suitability
reagent type: reductant
concentration
1.0 M in diethyl ether
density
0.716 g/mL at 25 °C
storage temp.
2-30°C
SMILES string
[Li+].[AlH4-]
InChI
1S/Al.Li.4H/q-1;+1;;;;
InChI key
OCZDCIYGECBNKL-UHFFFAOYSA-N
Application
- The preparation of thermoplastic polyester polyamides from oleic acid
- Lithium-polymer batteries
- Hydrodefluorination of gem-difluoromethylene derivatives
- Asymmetric aldol reactions
- Synthesis of Li-Al-N-H composites with hydrogen absorption / desorption properties
LAH is a powerful reducing agent for many different reduction reactions such as that of ketones to alcohols
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This Item | |||
|---|---|---|---|
| description 1.0 M in diethyl ether | description 2.0 M in THF | description 2.3 M in 2-methyltetrahydrofuran | description 0.5 M in 2-methoxyethyl ether |
| Quality Level 200 | Quality Level 200 | Quality Level 200 | Quality Level 100 |
| reaction suitability reagent type: reductant | reaction suitability reagent type: reductant | reaction suitability reagent type: reductant | reaction suitability reagent type: reductant |
| storage temp. 2-30°C | storage temp. 2-30°C | storage temp. 2-30°C | storage temp. 2-30°C |
| density 0.716 g/mL at 25 °C | density 0.906 g/mL at 25 °C | density 0.883 g/mL at 25 °C | density 0.95 g/mL at 25 °C |
| form liquid | form - | form liquid | form liquid |
| concentration 1.0 M in diethyl ether | concentration 2.0 M in THF | concentration 10 % (w/w), 2.3 M in 2-methyltetrahydrofuran | concentration 0.5 M in 2-methoxyethyl ether |
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signalword
Danger
target_organs
Central nervous system
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Irrit. 2 - STOT SE 3 - Water-react. 1
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