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Tetrabutylammonium tetrafluoroborate

99%, powder

Synonym(s):

Ammonium tetra-n-butyl tetrafluoroborate

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5 g

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$48.10
25 g

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$208.00
100 g

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$428.00
500 g

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$1,420.00
$1,065.00

About This Item

Linear Formula:
(CH3CH2CH2CH2)4N(BF4)
CAS Number:
Molecular Weight:
329.27
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352116
EC Number:
207-058-8
MDL number:
Beilstein/REAXYS Number:
3577508

$48.10


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Product Name

Tetrabutylammonium tetrafluoroborate, 99%

Quality Segment

assay

99%

form

powder

reaction suitability

core: ammonium, reaction type: phase-transfer

mp

155-161 °C (lit.)

solubility

methanol: soluble 10%, clear, colorless

SMILES string

F[B-](F)(F)F.CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/C16H36N.BF4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;/q+1;-1

InChI key

NNZZSJSQYOFZAM-UHFFFAOYSA-N

General description

Tetrabutylammonium tetrafluoroborate is used as an electrolyte for the series of arylketone synthesis.

Tetrabutylammonium tetrafluoroborate (TBATFB) is a phase transfer catalyst. It can be synthesized by the reaction between 30% aqueous solution of tetrafluoroboric acid and 40% aqueous solution of tetrabutylamonium hydroxide. Tetrabutylammonium tetrafluoroborate acts as an electrolyte and inhibits the self-assembly of alkylthiosulfate on gold.

Application

Tetrabutylammonium tetrafluoroborate may be used in the following studies:
  • As supporting electrolyte in the voltammetric determination of Δ(9)-tetrahydrocannabinol (Δ(9)-THC).
  • Synthesis of biologically relevant macrolactones, Sansalvamide A.
  • As supporting electrolyte in the determination of the oxidation and reduction potentials of 5,10,15,20-tetra[3-(3-trifluoromethyl)phenoxy]porphyrin by cyclic voltammetry.
  • Preparation of 1:1 adduct with 1,10-phenanthroline.
  • Used to prepare other tetrabutylammonium salts in aqueous solutions.
  • As electrolyte additive in the synthesis of conducting poly(thiophenes).

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This Item
8689686888
description

99%

description

for electrochemical analysis, ≥99.0%

description

≥99.0% (T)

assay

99%

assay

≥99.0%, ≥99.0% (T)

assay

≥99.0% (T)

reaction suitability

core: ammonium

reaction suitability

-

reaction suitability

core: ammonium

form

powder

form

crystals

form

crystals

Quality Level

200

Quality Level

200

Quality Level

100

mp

155-161 °C (lit.)

mp

159-162 °C, 155-161 °C (lit.)

mp

112-113 °C (lit.), 110-114 °C

solubility

methanol: soluble 10%, clear, colorless

solubility

methanol: 0.1 g/mL, clear, colorless

solubility

-


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Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

No data available

Flash Point (°C)

No data available

PPE (personal protective equipment)

dust mask type N95 (US), Eyeshields, Gloves



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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