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221171

Pinacol

98%

Synonym(s):

2,3-Dimethyl-2,3-butanediol, Tetramethylethylene glycol

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Size/SKUAvailabilityPrice
250 mg
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$16.60
$12.45
5 g
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$67.30
100 g
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$193.00
500 g
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$227.00

About This Item

Linear Formula:
HOC(CH3)2C(CH3)2OH
CAS Number:
Molecular Weight:
118.17
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-933-5
Beilstein/REAXYS Number:
1340501
MDL number:
Assay:
98%
Form:
solid

$12.45

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Quality Segment

assay

98%

form

solid

bp

171-172 °C/739 mmHg (lit.)

mp

40-43 °C (lit.)

solubility

alcohol: freely soluble, diethyl ether: freely soluble, hot water: freely soluble

functional group

hydroxyl

SMILES string

CC(C)(O)C(C)(C)O

InChI

1S/C6H14O2/c1-5(2,7)6(3,4)8/h7-8H,1-4H3

InChI key

IVDFJHOHABJVEH-UHFFFAOYSA-N

General description

The pinacol coupling reaction with the inorganic electride [Ca2N](+)·e(−) as an electron donor in organic solvents was studied.

Application

Pinacol is a 1,2-diol that can be used:
  • As a ligand to prepare uranyl complexes by reacting with uranyl nitrate and acetate hydrates.
  • To prepare pinacolone and 2,3-dimethyl-1,3-butadiene by typical pinacol rearrangement reaction.
  • As a reactant to synthesize 4-(4,4,5,5-tetramethyl-1,3,2-bioxaborolan-2-yl)benzoic acid, which is used to prepare derivatives of 4-acetoxy-3-phenylbenzaldehyde.


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This Item
647098163171724750
description

98%

description

97%

description

96%

description

97%

assay

98%

assay

97%

assay

96%

assay

97%

Quality Level

200

Quality Level

100

Quality Level

100

Quality Level

-

solubility

alcohol: freely soluble, hot water: freely soluble, diethyl ether: freely soluble

solubility

-

solubility

-

solubility

-

mp

40-43 °C (lit.)

mp

27-31 °C (lit.)

mp

220 °C (dec.) (lit.)

mp

>300 °C

bp

171-172 °C/739 mmHg (lit.)

bp

-

bp

-

bp

-

form

solid

form

solid

form

powder

form

solid


Storage Class

4.1B - Flammable solid hazardous materials

flash_point_f

170.6 °F - closed cup

flash_point_c

77 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

pictograms

FlameExclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Sol. 2 - Skin Irrit. 2



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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