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282774

Rhodium(III) acetylacetonate

97%

Synonym(s):

2,4-Pentanedione rhodium(III) derivative, Rh(acac)3

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250 mg
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$184.00
1 g
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$508.00
5 g
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$2,860.00

About This Item

Linear Formula:
[CH3COCH=C(O-)CH3]3Rh
CAS Number:
Molecular Weight:
400.23
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
238-192-5
MDL number:

$184.00


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Quality Segment

product line

Sol-Gel Precursors

assay

97%

form

solid

reaction suitability

reagent type: inorganic catalyst

mp

263-264 °C (lit.)

SMILES string

CC(=O)\C=C(/C)O[Rh](O\C(C)=C\C(C)=O)O\C(C)=C\C(C)=O

InChI

1S/3C5H8O2.Rh/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3+;

InChI key

DGOINFUDFBWCMX-MUCWUPSWSA-K

General description

Rhodium(III) acetylacetonate is a yellowcrystalline compound composed of rhodium atoms coordinated with three acetylacetonate ligands. It iswidely used in the field of catalysis, organic electronics and to prepare Rhcomplexes. It is soluble inorganic solvents.

Application

Rhodium(III) acetylacetonate can be used:
  • As a precursor to synthesize Rh nanocrystals with catalytic activities.
  • As an efficient catalyst for the α-alkylation of ketones, β-alkylation of secondary alcohols, and the alkylation of amines with primary alcohols.
  • To prepare highly phosphorescent complexes for organic light-emitting devices.
  • To synthesize the Rh2P NCs supported on carbon (Rh2P/C) by a one-step solvothermal method via a direct reaction between Rh(acac)3 and tri-n-octylphosphine (TOP). The resultant electrocatalyst exhibited remarkable performance for both the hydrogen evolution reaction and the oxygen evolution reaction, surpassing the capabilities of Rh/C and Pt/C catalysts for water splitting .
  • To prepare Single-atom Rh/N-doped carbon electrocatalyst for the oxidation of formic acid.
  • To synthesize Pt–Rh NWs as highly efficient electrocatalysts toward ethanol oxidation reaction (EOR) for Direct ethanol fuel cells. The electrocatalyst demonstrated improved catalytic activities, primarily attributed to the presence of Rh, which enhances its ability to resist poisoning.

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909556520772204226
description

97%

description

Umicore

description

crystalline, ≥99.9% trace metals basis

description

99.8%

assay

97%

assay

-

assay

≥99.9% trace metals basis

assay

99.8%

form

solid

form

powder

form

crystalline

form

powder

mp

263-264 °C (lit.)

mp

238 °C (decomp)

mp

100 °C (dec.) (lit.)

mp

-

Quality Level

100

Quality Level

-

Quality Level

100

Quality Level

100

reaction suitability

reagent type: catalyst

reaction suitability

-

reaction suitability

reagent type: catalyst, core: rhodium

reaction suitability

reagent type: catalyst
core: rhodium


Pictograms

Health hazardExclamation mark

Signal Word

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

dust mask type N95 (US), Eyeshields, Gloves



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