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283673

Copper(II) trifluoromethanesulfonate

98%

greener alternative

Greener Alternative

Synonym(s):

Cu(OTf)2, Copper(II) triflate, Cupric trifluoromethanesulfonate, Trifluoromethanesulfonic acid copper(II) salt

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Size/SKUAvailabilityPrice
5 g

Available to ship TODAYfromMILWAUKEE

$167.00
25 g

Available to ship TODAYfromMILWAUKEE

$469.00
$351.75

About This Item

Linear Formula:
(CF3SO3)2Cu
CAS Number:
Molecular Weight:
361.68
UNSPSC Code:
12161600
NACRES:
NA.22
PubChem Substance ID:
EC Number:
252-300-8
Beilstein/REAXYS Number:
4028198
MDL number:

$167.00


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Quality Segment

assay

98%

reaction suitability

core: copper, reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

≥300 °C

greener alternative category

SMILES string

FC(F)(F)S(=O)(=O)O[Cu]OS(=O)(=O)C(F)(F)F

InChI

1S/2CHF3O3S.Cu/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2

InChI key

SBTSVTLGWRLWOD-UHFFFAOYSA-L

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Green Chemistry. This catalyst promotes Friedel-Crafts reactions, aldol condensations, and cycloadditions with exceptional selectivity and water tolerance. Its compatibility with aqueous media eliminates anhydrous conditions and enables sustainable synthesis. Click here for more information.

Application

Catalyst for:
  • Mannich condensation
  • Annulative amination
  • Friedel-Crafts reaction
  • Henry reaction
  • Hypervalent iodine reagent-mediated preparation of carbazoles
  • Intramolecular oxidative C-N bond formation for the synthesis of carbazoles
Catalyzes the efficient addition of trimethylsilyl cyanide to carbonyl compounds.

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685038734527731722
description

98%

description

-

description

95%

description

97%

assay

98%

assay

-

assay

95%

assay

97%

reaction suitability

reagent type: catalyst, core: copper

reaction suitability

core: copper, reagent type: catalyst

reaction suitability

core: copper, reagent type: catalyst

reaction suitability

core: copper, reagent type: catalyst

Quality Level

200

Quality Level

100

Quality Level

100

Quality Level

100

mp

≥300 °C

mp

-

mp

190-194 °C

mp

105-110 °C

greener alternative category

Aligned

greener alternative category

-

greener alternative category

-

greener alternative category

-

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

-

greener alternative product characteristics

-

greener alternative product characteristics

-


Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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