If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
Select a Size
| Size/SKU | Availability | Price |
|---|---|---|
5 g | Check Cart for Availability | $47.50 |
100 g | Check Cart for Availability | $61.20 |
250 g | Check Cart for Availability | $136.00 |
500 g | Check Cart for Availability | $213.00 |
About This Item
$47.50
vapor pressure
23.3 mmHg ( 30 °C)
Quality Segment
assay
97%
form
solid
reaction suitability
reagent type: oxidant
mp
90-93 °C (lit.)
functional group
amine
storage temp.
room temp
SMILES string
OO.NC(N)=O
InChI
1S/CH4N2O.H2O2/c2-1(3)4;1-2/h(H4,2,3,4);1-2H
InChI key
AQLJVWUFPCUVLO-UHFFFAOYSA-N
General description
Application
- In the conversion of sulfides to sulfoxides or sulfones under solvent free condition.
- In the conversion of nitrogen heterocycles to their corresponding N-oxides.
- In the epoxidation of various alkene in combination with number of carboxylic anhydrides and disodium hydrogen phosphate in anhydrous organic solvents.
- In the Baeyer–Villiger oxidation reaction where in aldehydes and ketones undergo oxidation to produce esters and lactones using various peroxycarboxylic acids.
Features and Benefits
- Inexpensive.
- Stable.
- Easy handling reagent.
1 of 1
This Item | |||
|---|---|---|---|
| description 97% | description powder, 15-17% active oxygen basis | description 50 wt. % in H2O, stabilized | description contains inhibitor, 30 wt. % in H2O, meets USP testing specifications |
| assay 97% | assay - | assay 48-52% H2O2 basis (by KMnO4, titration) | assay ≤32% |
| Quality Level 200 | Quality Level 200 | Quality Level 100 | Quality Level 200 |
| reaction suitability reagent type: oxidant | reaction suitability reagent type: oxidant | reaction suitability reagent type: catalyst, reagent type: oxidant, reaction type: C-H Activation | reaction suitability reagent type: oxidant |
| storage temp. room temp | storage temp. - | storage temp. 2-8°C | storage temp. 2-8°C |
| mp 90-93 °C (lit.) | mp 85-90 °C (dec.), 90-93 °C (lit.) | mp −40 °C | mp - |
| form solid | form powder | form - | form liquid |
Signal Word
Danger
Hazard Codes
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Ox. Sol. 3 - Skin Irrit. 2
Storage Class
5.1B - Oxidizing hazardous materials
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
PPE (personal protective equipment)
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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