407240
Copper(I) trifluoromethanesulfonate benzene complex
90%, technical grade, powder
Greener Alternative
Synonym(s):
Copper(I) triflate benzene complex, Cuprous trifluoromethanesulfonate benzene complex, Trifluoromethanesulfonic acid copper(I) salt benzene complex
Select a Size
| Size/SKU | Availability | Price |
|---|---|---|
1 g | Available to ship TODAYfromMILWAUKEE | $88.00 $66.00 |
5 g | Available to ship TODAYfromMILWAUKEE | $153.00 |
About This Item
$66.00
List Price$88.00Save 25%Available to ship TODAYDetails
Product Name
Copper(I) trifluoromethanesulfonate benzene complex, technical grade, 90%
grade
technical grade
Quality Segment
assay
90%
form
powder
reaction suitability
core: copper, reagent type: catalyst
greener alternative product characteristics
Catalysis
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mp
160 °C (dec.) (lit.)
greener alternative category
SMILES string
[Cu+].[Cu+].c1ccccc1.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F
InChI
1S/C6H6.2CHF3O3S.2Cu/c1-2-4-6-5-3-1;2*2-1(3,4)8(5,6)7;;/h1-6H;2*(H,5,6,7);;/q;;;2*+1/p-2
InChI key
GNXZWVVAAMVOJY-UHFFFAOYSA-L
General description
Application
- To synthesize enol-esters via copper(I) carboxylate intermediate formation.
- In the enantioselective allylic oxidation of cyclic alkenes.
- To prepare 2,5-disubstituted pyrrolidine derivatives from N-alkenyl, alkynyl and alkyl N-benzoyloxysulfonamides via the sulfonamidyl radical formation.
It can also be used in combination with amino acid-based chiral phosphine ligands to catalyze asymmetric conjugate additions of alkylzincs to acyclic α,β-unsaturated ketones, affording β-alkylcarbonyls in high yield and with excellent enantioselectivity.
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This Item | |||
|---|---|---|---|
| description technical grade, 90% | description 99% | description 97% | description - |
| reaction suitability core: copper, reagent type: catalyst | reaction suitability reagent type: catalyst, core: copper | reaction suitability reagent type: catalyst, reagent type: catalyst | reaction suitability core: copper, reagent type: catalyst |
| assay 90% | assay 99% | assay 97% | assay - |
| form powder | form solid | form solid | form solid |
| Quality Level 100 | Quality Level 200 | Quality Level 100 | Quality Level 100 |
| mp 160 °C (dec.) (lit.) | mp 132 °C (dec.) (lit.) | mp 160 °C (dec.) (lit.) | mp - |
| greener alternative category | greener alternative category - | greener alternative category | greener alternative category - |
signalword
Warning
hcodes
Hazard Classifications
Flam. Sol. 2
Storage Class
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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