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455571

Potassium borohydride

≥97%

Synonym(s):

Potassium tetrahydroborate

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Size/SKUAvailabilityPrice
100 g
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$124.00
500 g
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$166.00
2 kg
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$472.00

About This Item

Linear Formula:
KBH4
CAS Number:
Molecular Weight:
53.94
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352306
EC Number:
237-360-5
MDL number:
Assay:
≥97%
Form:
powder

$124.00


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Quality Segment

assay

≥97%

form

powder

reaction suitability

reagent type: reductant

mp

500 °C (dec.) (lit.)

density

1.18 g/mL at 25 °C (lit.)

SMILES string

[K+].[H][B-]([H])([H])[H]

InChI

1S/BH4.K/h1H4;/q-1;+1

InChI key

ICRGAIPBTSPUEX-UHFFFAOYSA-N

Application

Potassium borohydride (KBH4) can be used as a reducing agent for the synthesis of:       
  • Copper nanoparticles by the reduction of copper salts.
  •  Enantioselective allylic alcohols by the catalytic reduction of enones and ketones in the presence of chiral N,N′-dioxidescandium(III) complex catalyst.,·        
  • Azoxybenzenes by the reduction of nitroarenes in the presence of phase transfer catalyst PEG-400.

It can also be employed as a boron source in the nickel–boron alloy, which is electrodeposited on carbon fiber to improve catalytic graphitization of carbon.

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This Item
438472P378660080
description

≥97%

description

99.9% trace metals basis

description

ACS reagent, ≥98%

description

purum, ≥97.0% (RT)

form

powder

form

powder

form

powder

form

-

assay

≥97%

assay

99.9% trace metals basis

assay

≥98%

assay

≥97.0% (RT)

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

100

mp

500 °C (dec.) (lit.)

mp

500 °C (dec.) (lit.)

mp

-

mp

500 °C (dec.) (lit.)

density

1.18 g/mL at 25 °C (lit.)

density

1.18 g/mL at 25 °C (lit.)

density

-

density

1.18 g/mL at 25 °C (lit.)

reaction suitability

reagent type: reductant

reaction suitability

reagent type: reductant, core: potassium

reaction suitability

-

reaction suitability

reagent type: reductant


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Signal Word

Danger

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

nwg

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Repr. 1B - Skin Corr. 1B - Water-react. 1



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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