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593702

Lithium aluminum hydride solution

2.0 M in THF

Synonym(s):

LAH, Lithium alanate, Lithium tetrahydroaluminate

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Size/SKUAvailabilityPrice
100 mL

Available to ship TODAYfromMILWAUKEE

$92.80
4 x 25 mL

Available to ship TODAYfromMILWAUKEE

$93.70
1 L

Available to ship TODAYfromMILWAUKEE

$560.00

About This Item

Linear Formula:
LiAlH4
CAS Number:
Molecular Weight:
37.95
NACRES:
NA.22
PubChem Substance ID:
MDL number:
UNSPSC Code:
12352401

$92.80


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Quality Segment

reaction suitability

reagent type: reductant

concentration

2.0 M in THF

density

0.906 g/mL at 25 °C

storage temp.

2-30°C

SMILES string

[Li+].[AlH4-]

InChI

1S/Al.Li.4H/q-1;+1;;;;

InChI key

OCZDCIYGECBNKL-UHFFFAOYSA-N

Application

Reactant or reagent for:
  • The preparation of thermoplastic polyester polyamides from oleic acid
  • Lithium-polymer batteries
  • Hydrodefluorination of gem-difluoromethylene derivatives
  • Asymmetric aldol reactions
  • Synthesis of Li-Al-N-H composites with hydrogen absorption / desorption properties

LAH is a powerful reducing agent for many different reduction reactions such as that of ketones to alcohols

Packaging

The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

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This Item
703508236055323403
description

2.0 M in THF

description

2.3 M in 2-methyltetrahydrofuran

description

0.5 M in 2-methoxyethyl ether

description

pellets, reagent grade, 95%

reaction suitability

reagent type: reductant

reaction suitability

reagent type: reductant

reaction suitability

reagent type: reductant

reaction suitability

reagent type: reductant

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

200

concentration

2.0 M in THF

concentration

10 % (w/w), 2.3 M in 2-methyltetrahydrofuran

concentration

0.5 M in 2-methoxyethyl ether

concentration

-

density

0.906 g/mL at 25 °C

density

0.883 g/mL at 25 °C

density

0.95 g/mL at 25 °C

density

-

storage temp.

2-30°C

storage temp.

2-30°C

storage temp.

2-30°C

storage temp.

-


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signalword

Danger

target_organs

Central nervous system, Respiratory system

supp_hazards

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

flash_point_f

-13.0 °F - closed cup

flash_point_c

-25 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3 - Water-react. 1



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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