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75990

Palladium on activated charcoal

10% Pd, powder

greener alternative

Greener Alternative

Synonym(s):

Pd/C

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Size/SKUAvailabilityPrice
1 g
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$59.00
10 g
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$411.00
50 g
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$1,870.00

About This Item

Linear Formula:
Pd
UNSPSC Code:
12141733
eCl@ss:
38191001
PubChem Substance ID:
NACRES:
NA.22
MDL number:

$59.00


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Product Name

Palladium on activated charcoal, 10% Pd basis

Quality Segment

form

powder

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

greener alternative product characteristics

Designing Safer Chemicals
Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentration

10% Pd

greener alternative category

SMILES string

[Pd]

InChI

1S/Pd

InChI key

KDLHZDBZIXYQEI-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Palladium on activated charcoal has been used for the reduction of trimesic acid to form a mixture of cis,cis and cis,trans isomers of 1,3,5-cyclohexanetricarboxylic acid. It can also be used for the conversion of benzylic and allylic alcohols into the corresponding carbonyl compounds in the presence of olefins as hydrogen acceptors.

Other Notes

Catalyst for dehydrogenations

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This Item
759917599376063
description

10% Pd basis

description

moistened with water, 5% Pd basis (based on dry substance)

description

moistened with water, 10% Pd basis (based on dry substance)

description

moistened with water, 10-20% Pd basis (based on dry substance)

reaction suitability

core: palladium, reaction type: Heck Reaction, reaction type: Negishi Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Suzuki-Miyaura Coupling, reaction type: Sonogashira Coupling, reaction type: Hiyama Coupling, reaction type: Stille Coupling, reagent type: catalyst

reaction suitability

reaction type: Heck Reaction, reaction type: Stille Coupling, core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Hiyama Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Negishi Coupling, reagent type: catalyst, reaction type: Sonogashira Coupling

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Negishi Coupling, reaction type: Heck Reaction, reaction type: Suzuki-Miyaura Coupling, reaction type: Hiyama Coupling, core: palladium, reaction type: Stille Coupling, reaction type: Sonogashira Coupling, reagent type: catalyst

reaction suitability

reaction type: Hiyama Coupling, reaction type: Stille Coupling, reaction type: Heck Reaction, core: palladium, reagent type: catalyst, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction

form

powder

form

paste

form

paste

form

lumps

Quality Level

200

Quality Level

100

Quality Level

100

Quality Level

100

sustainability

Greener Alternative Product

sustainability

Greener Alternative Product

sustainability

Greener Alternative Product

sustainability

Greener Alternative Product

concentration

10% Pd

concentration

5% Pd (based on dry substance)

concentration

10% Pd

concentration

10-20% Pd (based on dry substance)

greener alternative product characteristics

Designing Safer Chemicals
Catalysis
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Designing Safer Chemicals
Catalysis
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Designing Safer Chemicals
Catalysis
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Designing Safer Chemicals
Catalysis
Learn more about the Principles of Green Chemistry.


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Pictograms

Exclamation mark

Signal Word

Warning

Hazard Codes

Precautionary Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

Eyeshields, Gloves, type N95 (US)



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Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. Can you please tell me what is the particle size of Product 75991, Palladium on activated charcoal - moistened with water, 5% Pd basis?

    1 answer
    1. The average particle size for this product is 19um. The cumulative particle size distribution is as follows:
      1% >70um
      6% > 60um
      17% > 50um
      24% > 40um
      34% > 30um
      49% > 20um
      74% > 10um
      94% > 5um
      98.5% > 3um
      100% > 2um

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