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121908

Neocuproine hydrate

99%

Synonym(s):

2,9-Dimethyl-1,10-phenanthroline hydrate

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5 g

Available to ship TODAYfromMILWAUKEE

$69.90
25 g

Available to ship TODAYfromMILWAUKEE

$291.00

About This Item

Empirical Formula (Hill Notation):
C14H12N2 · xH2O
CAS Number:
654054-57-6
Molecular Weight:
208.26 (anhydrous basis)
NACRES:
NA.22
PubChem Substance ID:
24847471
UNSPSC Code:
12352100
EC Number:
207-601-9
MDL number:
MFCD00149306
Assay:
99%

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Quality Level

100

assay

99%

solubility

methanol: soluble 50 mg/mL, clear, colorless to dark yellow

SMILES string

[H]O[H].Cc1ccc2ccc3ccc(C)nc3c2n1

InChI

1S/C14H12N2.H2O/c1-9-3-5-11-7-8-12-6-4-10(2)16-14(12)13(11)15-9;/h3-8H,1-2H3;1H2

InChI key

MFZBSWSCIWCRKS-UHFFFAOYSA-N

General description

Neocuproine hydrate is chelating agent and forms complex with Cu+ formed by reduction of Cu+2 by hydroxylamine hydrochloride and produces electrochemiluminescence. It is an efficient ligand for alcohol oxidation with palladium in 1:1 water/DMSO mixtures.

Application

Neocuproine hydrate was used in determination of copper ions in aqueous solution using electrochemiluminescence.

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Neocuproine hydrate 99%

Sigma-Aldrich

121908

Neocuproine hydrate

Neocuproine hydrochloride hydrate BioReagent, crystalline

Sigma-Aldrich

N1626

Neocuproine hydrochloride hydrate

Bathophenanthrolinedisulfonic acid disodium salt hydrate 98%

Sigma-Aldrich

146617

Bathophenanthrolinedisulfonic acid disodium salt hydrate

Neocuproine ≥98%

Sigma-Aldrich

N1501

Neocuproine

assay

99%

assay

-

assay

98%

assay

≥98%

solubility

methanol: soluble 50 mg/mL, clear, colorless to dark yellow

solubility

-

solubility

water: soluble 100 mg/mL, clear to slightly hazy, yellow (to red)

solubility

-

Quality Level

100

Quality Level

200

Quality Level

100

Quality Level

200

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
SDBB2261
STBL3593
STBL0095
STBJ1509
STBJ0462

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Determining copper ions in water using electrochemiluminescence.
High B, et al.
Analytica Chimica Acta, 449(1), 17-22 (2001)
Catalytic Conversions in Water. Part 23: Steric Effects and Increased Substrate Scope in the Palladium-Neocuproine Catalyzed Aerobic Oxidation of Alcohols in Aqueous Solvents#.
Brink GJ, et al.
Advanced Synthesis & Catalysis, 345(12), 1341-1352 (2003)

Global Trade Item Number

SKUGTIN
121908-25G04061833020722
121908-5G04061838719713

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