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15380

Boc-Ala-OH

≥99.0% (TLC), for peptide synthesis

Synonym(s):

N-(tert-Butoxycarbonyl)-L-alanine, Boc-L-alanine

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Size/SKUAvailabilityPrice
5 g

Available to ship TODAYfromMILWAUKEE

$39.90
25 g

Available to ship TODAYfromMILWAUKEE

$124.00
100 g

Available to ship TODAYfromMILWAUKEE

$182.00

About This Item

Linear Formula:
CH3CH[NHCO2C(CH3)3]CO2H
CAS Number:
Molecular Weight:
189.21
EC Number:
239-847-8
MDL number:
Beilstein/REAXYS Number:
1726365
NACRES:
NA.22
PubChem Substance ID:
eCl@ss:
32160406
UNSPSC Code:
12352209

$39.90


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Product Name

Boc-Ala-OH, ≥99.0% (TLC)

Quality Segment

assay

≥99.0% (TLC)

optical activity

[α]20/D −25±1°, c = 2% in acetic acid

reaction suitability

reaction type: Boc solid-phase peptide synthesis, reaction type: C-H Activation, reagent type: ligand
reaction type: Peptide Synthesis

mp

79-83 °C (lit.)

application(s)

peptide synthesis

functional group

amine, carboxylic acid

SMILES string

C[C@H](NC(=O)OC(C)(C)C)C(O)=O

InChI

1S/C8H15NO4/c1-5(6(10)11)9-7(12)13-8(2,3)4/h5H,1-4H3,(H,9,12)(H,10,11)/t5-/m0/s1

InChI key

QVHJQCGUWFKTSE-YFKPBYRVSA-N

Application

Boc-Ala-OH can be used:
  • In the preparation of N-propargylalanine, a key precursor to generate N-(3-aryl)propylated alanine residues.
  • In the resolution of racemic mixture of 3,3′-bis(benzyloxy)-1,1′-binaphthalene-2,2′-diol.
  • In the one-pot synthesis of hybrid tripeptidomimetics containing both amide and imide functionalities.


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This Item
15480531480492884
description

≥99.0% (TLC)

description

≥99.0% (T)

description

95%

description

99.9 atom % 12C

assay

≥99.0% (TLC)

assay

≥99.0% (T)

assay

95%

assay

-

functional group

amine, carboxylic acid

functional group

carboxylic acid, amine

functional group

Fmoc, carboxylic acid, amine

functional group

Boc

mp

79-83 °C (lit.)

mp

85-87 °C (lit.)

mp

147-153 °C (lit.)

mp

79-83 °C (lit.)

optical activity

[α]20/D −25±1°, c = 2% in acetic acid

optical activity

[α]20/D +25±1°, c = 1% in ethanol

optical activity

[α]20/D −18°, c = 1 in DMF

optical activity

[α]20/D -23°, c = 2 in acetic acid

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

200

application(s)

peptide synthesis

application(s)

peptide synthesis

application(s)

peptide synthesis

application(s)

peptide synthesis


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Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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