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164577

Tritylium tetrafluoroborate

Synonym(s):

Triphenylcarbenium tetrafluoroborate, Trityl fluoroborate

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Size/SKUAvailabilityPrice
5 g
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$65.00
25 g
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$238.00

About This Item

Linear Formula:
(C6H5)3C(BF4)
CAS Number:
Molecular Weight:
330.13
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
EC Number:
206-433-3
Beilstein/REAXYS Number:
3659536
MDL number:
Form:
solid

$65.00


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form

solid

Quality Segment

reaction suitability

reagent type: oxidant

mp

205-215 °C (dec.) (lit.)

functional group

phenyl

storage temp.

2-8°C

SMILES string

F[B-](F)(F)F.c1ccc(cc1)[C+](c2ccccc2)c3ccccc3

InChI

1S/C19H15.BF4/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;2-1(3,4)5/h1-15H;/q+1;-1

InChI key

VQXBOEYKSVVPSP-UHFFFAOYSA-N

Application

Reactant involved in:
  • Synthesis of substituted dihydroazulene photoswitches
  • Carbene-based Lewis pairs for hydrogen activation
  • 1,3-Dipolar cycloaddition reactions for preparation of α−amino-β-hydroxy esters
  • Oxidation of allenic compounds
  • Mukaiyama aldol addition reactions
  • Ionic hydrogenation as a counteranion and ligand source

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This Item
CIAH9C1164E0AMBH99C017C9ALNH9AA09DF3
description

-

description

-

description

-

description

-

reaction suitability

reagent type: oxidant

reaction suitability

-

reaction suitability

-

reaction suitability

-

Quality Level

200

Quality Level

-

Quality Level

-

Quality Level

-

form

solid

form

-

form

-

form

-

storage temp.

2-8°C

storage temp.

-

storage temp.

-

storage temp.

-

mp

205-215 °C (dec.) (lit.)

mp

-

mp

-

mp

-

functional group

phenyl

functional group

-

functional group

-

functional group

-


Pictograms

Corrosion

Signal Word

Danger

Hazard Codes

Hazard Classifications

Skin Corr. 1B

supp_hazards

Storage Class

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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