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208795

S-Methyl methanethiosulfonate

97%

Synonym(s):

S-Methyl thiomethanesulfonate, MMTS

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Size/SKUAvailabilityPrice
1 g
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$49.60
10 g
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$255.00

About This Item

Linear Formula:
CH3SO2SCH3
CAS Number:
Molecular Weight:
126.20
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
220-970-0
Beilstein/REAXYS Number:
1446059
MDL number:
Assay:
97%
Form:
liquid

$49.60


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Quality Segment

assay

97%

form

liquid

refractive index

n20/D 1.513 (lit.)

bp

69-71 °C/0.4 mmHg (lit.)

solubility

DMF: soluble 1:1, chloroform: soluble 200 ul per mL, clear, faintly yellow-green, water: soluble 1:5

density

1.337 g/mL at 25 °C (lit.)

functional group

disulfide

SMILES string

CSS(C)(=O)=O

InChI

1S/C2H6O2S2/c1-5-6(2,3)4/h1-2H3

InChI key

XYONNSVDNIRXKZ-UHFFFAOYSA-N

General description

S-Methyl methanethiosulfonate is a reagent used to synthesize thiols and thioesters. Used as cross-linking agent to prepare polymer networks. Interaction of S-methyl methanethiosulfonate (MMTS) with dipalmitoylphosphatidylcholine (DPPC) bilayers has been investigated by FTIR and surface-enhanced Raman spectroscopy.

Application

S-Methyl methanethiosulfonate was used as sulfenylating agent for β-keto sulfoxides, methylene compounds, half-esters of malonic acids and aryl Grignard reagents. It was also used as a reagent to trap the natural thiol-disulfide state of the proteins.

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This Item
64306390267930059
description

97%

description

purum, ≥98.0% (GC)

description

99%

description

-

assay

97%

assay

≥98.0% (GC)

assay

99%

assay

-

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

100

solubility

water: soluble 1:5, DMF: soluble 1:1, chloroform: soluble 200 ul per mL, clear, faintly yellow-green

solubility

chloroform: 750mg + 5 ml Chloroform mg/mL, colorless to light greenish-yellow

solubility

-

solubility

-

refractive index

n20/D 1.513 (lit.)

refractive index

n20/D 1.513

refractive index

-

refractive index

n/D 1.586

bp

69-71 °C/0.4 mmHg (lit.)

bp

69-71 °C/0.4 mmHg (lit.)

bp

-

bp

-

form

liquid

form

-

form

-

form

liquid


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PPE (personal protective equipment)

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Pictograms

Skull and crossbones

Signal Word

Danger

Hazard Codes

Hazard Classifications

Acute Tox. 3 Oral - Skin Sens. 1



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Questions

1–4 of 4 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. What is the storage temperature of S-Methyl methanethiosulfonate 97% (Product No. 208795)?

    1 answer
    1. This product may be stored in room temperature.

      Helpful?

  3. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  4. What is the molarity of this reagent?

    1 answer
    1. The material is considered neat/pure (i.e. it is not a solution), so the molarity would be 10.59 molar, multiplied by whatever the lot-specific purity is, which can be found on the COA. The molarity value was determined by dividing the density by the molecular weight and correcting for units.

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