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220809

Diethylzinc solution

15 wt. % in toluene

Synonym(s):

Zincdiethyl

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Size/SKUAvailabilityPrice
100 g

Available to ship TODAYfromMILWAUKEE

$208.00
800 g

Available to ship TODAYfromMILWAUKEE

$994.00

About This Item

Linear Formula:
(C2H5)2Zn
CAS Number:
Molecular Weight:
123.51
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587207

$208.00


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form

liquid

Quality Segment

concentration

15 wt. % in toluene

density

0.915 g/mL at 25 °C

SMILES string

CC[Zn]CC

InChI

1S/2C2H5.Zn/c2*1-2;/h2*1H2,2H3;

InChI key

HQWPLXHWEZZGKY-UHFFFAOYSA-N

Application

Employed together with CF3I in a Rh(I) catalyzed preparation of α-trifluoromethyl ketones from α,β-unsaturated ketones. Promoter for the Wittig reaction of carbonyl compounds with dibromofluoroacetate and triphenylphosphine leading to α-fluroroacrylates. Ni catalyzed coupling with cyclic anhydrides.

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This Item
296112256781668729
description

15 wt. % in toluene

description

1.0 M in hexanes

description

≥52 wt. % Zn basis

description

packaged for use in deposition systems

density

0.915 g/mL at 25 °C

density

0.726 g/mL at 25 °C

density

1.205 g/mL at 25 °C (lit.)

density

1.205 g/mL at 25 °C (lit.)

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

concentration

15 wt. % in toluene

concentration

1.0 M in hexanes

concentration

≥52 wt. % Zn

concentration

-

form

liquid

form

-

form

liquid

form

liquid


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Signal Word

Danger

Target Organs

Central nervous system

supp_hazards

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 3

Flash Point (°F)

44.6 °F - closed cup

Flash Point (°C)

7 °C - closed cup

PPE (personal protective equipment)

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Hazard Classifications

Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3 - Water-react. 1



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